Synthesis and Crystal Structure of Bis[N-{(S)-1-Phenylethyl}-N-{1-(2-Pyridinyl)Methyl}Amine] Zinc(II) Perchlorate

被引：0
|
作者：
Nguyen, Quang Trung [1 ]
Jeong, Jong Hwa [1 ]
机构：
[1] Kyungpook Natl Univ, Dept Chem, Taegu 702701, South Korea
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 04期
关键词：
X-ray crystal structure; Bis[N-{(S)-1-phenylethyl}-N-{1-(2-pyridinyl)methyl}amine]Zn complex; (R)-coordination; TRANSFER HYDROGENATION; NITROALDOL REACTION; COMPLEXES; LIGANDS;
D O I：
10.1007/s10870-009-9663-4
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The reaction of N-[(S)-1-phenylethyl]-N-[1-(2-pyridinyl)methyl]amine (PEPMA) with Zn(ClO4)(2) affords (PEPMA)(2)Zn(ClO4)(2) at room temperature. The complex is characterized by elemental analysis, H-1-MNR and X-ray crystallography. The crystal system is orthorhombic with space group of P2(1)2(1)2(1) and unit cell parameters: a = 8.6911(4), b = 9.7755(7), c = 37.275(2) angstrom, V = 3166.9(3) A(3), Z = 4, D-x = 1.445 Mg/m(3). The crystal structure reveals that zinc metal is ligated by two PEPMA ligands in a distorted tetrahedral fashion. Interestingly, both nitrogen atoms of amine at PEPMA to the central zinc metal exhibit (R)-configuration.
引用
收藏
页码：373 / 375
页数：3
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