FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O

被引：7
作者：
Il'in, M. A. [1 ,2 ]
Emel'yanov, V. A. [1 ,2 ]
Baidina, I. A. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 51卷 / 01期
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction analysis; IR spectroscopy; SPECTRA;
D O I：
10.1007/s10947-010-0014-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of the interaction products of (NH4)(2)[Ru(NO)Cl-5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)(3)(H2O)Cl][Ru(NO)(NH3)(3)(OH)Cl] x [Ru(NO)(NH3)Cl-4](2)Cl center dot 2H(2)O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) angstrom, b = 8.202(2) angstrom, c = 11.844(2) angstrom; beta = 101.54(3)degrees.
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页码：99 / 106
页数：8
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