FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O

被引：7
作者：
Il'in, M. A. [1 ,2 ]
Emel'yanov, V. A. [1 ,2 ]
Baidina, I. A. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2010年 / 51卷 / 01期
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction analysis; IR spectroscopy; SPECTRA;
D O I：
10.1007/s10947-010-0014-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of the interaction products of (NH4)(2)[Ru(NO)Cl-5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)(3)(H2O)Cl][Ru(NO)(NH3)(3)(OH)Cl] x [Ru(NO)(NH3)Cl-4](2)Cl center dot 2H(2)O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) angstrom, b = 8.202(2) angstrom, c = 11.844(2) angstrom; beta = 101.54(3)degrees.
引用
收藏
页码：99 / 106
页数：8
相关论文
共 36 条
[1]  
BALAKAEVA TA, 2001, ZH NEORG KHIM, V0046
[2]   Water π-donation in trans-tetraammineruthenium(II):: Effect on coordinated-water properties induced by a trans NO ligand [J].
Bezerra, CWB ;
da Silva, SC ;
Gambardella, MTP ;
Santos, RHA ;
Plicas, LMA ;
Tfouni, E ;
Franco, DW .
INORGANIC CHEMISTRY, 1999, 38 (25) :5660-5667
[3]   REINVESTIGATION OF CRYSTAL AND MOLECULAR-STRUCTURES OF PENTAAMMINENITROSYLRUTHENIUM TRICHLORIDE HYDRATE AND TRANS-TETRA-AMMINE-HYDROXONITROSYLRUTHENIUM DICHLORIDE [J].
BOTTOMLEY, F .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (15) :1600-1605
[4]   Ruthenium metallopharmaceuticals [J].
Clarke, MJ .
COORDINATION CHEMISTRY REVIEWS, 2002, 232 (1-2) :69-93
[5]   Crystal structure of ammonium pentachloroaquaruthenate(III) (NH4)2[Ru(H2O)Cl5] [J].
Emel'yanov, V. A. ;
Virovets, A. V. ;
Baidina, I. A. .
JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (03) :566-569
[6]   Synthesis and crystal structure of nitrosoruthenium aquadiammine complex, [Ru(NO)(NH3)2Cl2(H2O)]Cl•H2O [J].
Emel'yanov, V. A. ;
Baidina, I. A. ;
Il'in, M. A. ;
Gromilov, S. A. .
JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 47 (02) :380-382
[7]   Tetrabutylammonium salts of ruthenium(II) nitroso complexes [J].
Emel'yanov, VA ;
Baidina, IA ;
Khranenko, SP ;
Gromilov, SA ;
Il'in, MA ;
Belyaev, AV .
JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 44 (01) :37-45
[8]   Synthesis, formation mechanism, and crystal structure of the nitrosoruthenium(II) nitrochloride complex fac-K2[RuNO(NO2)2Cl3] [J].
Emel'yanov, VA ;
Baidina, IA ;
Gromilov, SA ;
Virovets, AV ;
Belyaev, AV .
JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 43 (02) :304-311
[9]   Synthesis and crystal structure of nitrosoruthenium triammino complex [RuNO(NH3)3Cl(H2O)]Cl2 [J].
Emel'yanov, VA ;
Baidina, IA ;
Gromilov, SA ;
Vasiliev, AD ;
Belyaev, AV .
JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 41 (06) :1030-1034
[10]  
Emel'yanov VA, 2001, RUSS J INORG CHEM+, V46, P346
1234