A magnetic nanoparticle-catalyzed regioselective ring opening of epoxides by aromatic amines

被引：9

作者：

Azizi, Najmedin ^{[1
]}

Kamrani, Parisa ^{[1
]}

Saadat, Mostafa ^{[1
]}

机构：

[1] Chem & Chem Engn Res Ctr Iran, POB 14335-186, Tehran, Iran

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2016年 / 30卷 / 06期

关键词：

magnetic Fe3O4 nanoparticle; epoxide; aromatic amine; nanocatalyst; HIGHLY EFFICIENT SYNTHESIS; IRON-OXIDE NANOPARTICLES; AMINOLYSIS; ALCOHOLS;

D O I：

10.1002/aoc.3450

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Sulfonic acid-functionalized silica-coated magnetic Fe3O4 nanoparticles were synthesized and applied as a green catalyst for an efficient and environmentally friendly ring opening of epoxides with aromatic amines in good to excellent yields with high chemoselectivity. Clean aminolysis of various aliphatic and aromatic epoxides in ethanol generates beta-hydroxyamines under mild reaction conditions. The synthesized acidic magnetic nanoparticles were recovered using a simple external magnet and successfully reused for five runs without any appreciable loss of catalytic activity. Copyright (C) 2016 John Wiley & Sons, Ltd.

引用

页码：431 / 434

页数：4

共 34 条

[31] D-Glucosamine in iron-catalysed cross-coupling reactions of Grignards with allylic and vinylic bromides: application to the synthesis of a key sitagliptin precursor [J].

Sova, Matej ;

Frlan, Rok ;

Gobec, Stanislav ;

Stavber, Gaj ;

Casar, Zdenko .

APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (08) :528-535

[32] Porous Nanosized Particles: Preparation, Properties, and Applications [J].

Valtchev, Valentin ;

Tosheva, Lubomira .

CHEMICAL REVIEWS, 2013, 113 (08) :6734-6760

[33] Nano n-propylsulfonated γ-Al2O3: a new, efficient and reusable catalyst for synthesis of spiro[indoline-3,4-pyrazolo[3,4-e][1,4]thiazepine]diones in aqueous media [J].

Wu, Li Qiang .

APPLIED ORGANOMETALLIC CHEMISTRY, 2013, 27 (03) :148-154

[34]

Yadav G.D., 2014, SYNTHESIS-STUTTGART, P629

← 1 2 3 4 →