Thallium(III) in Organic Synthesis

被引：19
作者：
Silva, Luiz F., Jr. [1 ]
Carneiro, Vania M. T. [1 ]
机构：
[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil
来源：
SYNTHESIS-STUTTGART | 2010年 / 07期
基金：
巴西圣保罗研究基金会;
关键词：
thallium(III); rearrangement; coupling; cyclization; oxidation; MEDIATED RING CONTRACTION; DIASTEREOSELECTIVE TOTAL-SYNTHESIS; ETA(5)-CYCLOPENTADIENYL DERIVATIVES; OXIDATIVE REARRANGEMENT; HOMOALLYLIC ALCOHOLS; FACILE SYNTHESIS; ELECTROCHEMICAL PROPERTIES; ANTIBODY RECOGNITION; SECONDARY ANILINES; INDANS BEARING;
D O I：
10.1055/s-0029-1218669
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review article discusses the literature regarding thallium(III) compounds in synthetic organic chemistry published in the last decade, including several applications in the total synthesis of natural products. The reactions that received the most attention in this period were: i) the oxidative rearrangement of chalcones; ii) the ring contraction of cyclic alkenes; iii) the oxidation of homoallylic alcohols; iv) aromatic thallations; and v) oxidative couplings, including with phenols.
引用
收藏
页码：1059 / 1074
页数：16
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