Chlorido(η5-pentamethylcyclopentadienyl)-(1,10-phenanthroline-k2N,N′) iridium(III) trifluoromethanesulfonate

被引：7

作者：

Scharwitz, Michael ^{[1
]}

Schaefer, Sven ^{[1
]}

van Almsick, Tobias ^{[1
]}

Sheldrick, William S. ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Analyt Chem, D-44780 Bochum, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

CARBONYL-COMPOUNDS; COMPLEXES; WATER;

D O I：

10.1107/S1600536807011750

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The cation of the title compound, [Ir(eta(5) - C5Me5)Cl(C12H8N2)]-CF3SO3, contains a half-sandwich (eta(5)-C5Me5)Ir-III fragment coordinated in a kappa N-2 manner by the N atoms of a 1,10-phenanthroline ligand. The diimine ligand is inclined at an angle of 62.6 (4)degrees to the plane of the pentamethylcyclopentadienyl ligand.

引用

页码：M1111 / M1113

页数：3

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