Reduction of 1,1′-binaphthyls to octahydro-1,1′-binaphthyl derivatives with Raney Ni-Al alloy in aqueous solution

被引：55

作者：

Guo, H ^{[1
]}

Ding, KL ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Organomet Chem Lab, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 51期

基金：

中国国家自然科学基金;

关键词：

binaphthyls; octahydrobinaphthyls; reduction; Ni-Al; chiral;

D O I：

10.1016/S0040-4039(00)01799-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reduction of BINOL, BINAM and NOBIN with Raney Ni-Al alloy in dilute NaOH aqueous solution results in the formation of H-8-BINOL, H-8-BINAM and H-8-NOBIN in 60-86% isolated yields with 97.5-99% enantiomeric excesses. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：10061 / 10064

页数：4

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