We numerically calculate the configurational entropy S-conf of a binary mixture of hard spheres, by using a perturbed Hamiltonian method trapping the system inside a given state, which requires fewer assumptions than the previous methods (Speedy 1998 Mol. Phys. 95 169). We find that Sconf is a decreasing function of the packing fraction. and extrapolates to zero at the Kauzmann packing fraction phi K similar or equal to 0.62, suggesting the possibility of an ideal glass transition for the hard-sphere system. Finally, the Adam-Gibbs relation is found to hold.
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Harvard Univ, Program Evolutionary Dynam, Cambridge, MA 02138 USAHarvard Univ, Program Evolutionary Dynam, Cambridge, MA 02138 USA
Antal, T.
Krapivsky, P. L.
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Boston Univ, Dept Phys, Boston, MA 02215 USA
Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USAHarvard Univ, Program Evolutionary Dynam, Cambridge, MA 02138 USA
Krapivsky, P. L.
Redner, S.
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Boston Univ, Dept Phys, Boston, MA 02215 USA
Boston Univ, Ctr Polymer Studies, Boston, MA 02215 USAHarvard Univ, Program Evolutionary Dynam, Cambridge, MA 02138 USA