CRYSTAL STRUCTURE OF NEW AMMONIUM FLUOROINDATE(III) (NH4)2[InF5]

被引：4

作者：

Davidovich, R. L. ^{[1
]}

Logvinova, V. B. ^{[1
]}

Tkachev, V. V. ^{[2
]}

Shilov, G. V. ^{[2
]}

机构：

[1] Russian Acad Sci, Far Eastern Branch, Inst Chem, Vladivostok, Russia

[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 03期

关键词：

synthesis; indium(III); complex fluoride; ammonium; octahedron; polymer chain; crystal structure; INDIUM FLUORIDE;

D O I：

10.1134/S0022476617030192

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new indium(III) fluoride complex with the ammonium cation (NH4)(2)[InF5] is synthesized and its crystal structure is studied. The structure of (NH4)(2)[InF5] is formed of NH4+ cations and complex [InF5](2-) anions. The In atom in the complex anion surrounded by four terminal and two bridging F atoms forms an almost regular octahedral coordination polyhedron (CN 6) with two terminal F atoms in the axial positions and two terminal and two bridging F atoms in the equatorial plane. Through bridging F atoms, the InF6 polyhedra are arranged in polymer trans- vertex-connected corrugated anion chains (InF5)(n)(2n-) directed along the c axis. The N-H center dot center dot center dot F hydrogen bonds organize the chains in a three-dimensional framework.

引用

页码：585 / 587

页数：3

共 11 条

[1] THERMAL-DECOMPOSITION OF AMMONIUM HEXAFLUOROGALLATE AND AMMONIUM HEXAFLUOROINDATE - NEW CRYSTALLINE FORMS OF GALLIUM FLUORIDE AND INDIUM FLUORIDE [J].

BECK, LK ;

KUGLER, BH ;

HAENDLER, HM .

JOURNAL OF SOLID STATE CHEMISTRY, 1973, 8 (04) :312-317

[2] STRUKTUREN DER HEXAFLUOROMETALLATE(III) [J].

BODE, H ;

VOSS, E .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1957, 290 (1-2) :1-16

[3]

CHAMPARN.JC, 1974, CR ACAD SCI C CHIM, V278, P171

[4]

Deichman E. N., 1967, ZH NEORG KHIM, V12, P307

[5] Solvothermal Synthesis and Luminescent Properties of Two Organically Templated Chain-Structure Fluorides, [C4H14N2][MF5] (M = In, Sc) [J].

Jayasundera, Anil C. A. ;

Finch, Adrian A. ;

Wormald, Philip ;

Lightfoot, Philip .

CHEMISTRY OF MATERIALS, 2008, 20 (21) :6810-6815

[6] Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, β-(NH4)3InF6 and [NH4]3[C6H21N4]2[In4F21] [J].

Jayasundera, Anil C. A. ;

Goff, Richard J. ;

Li, Yang ;

Finch, Adrian A. ;

Lightfoot, Philip .

JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (02) :356-360

[7] Indium(III) Coordination Compounds [J].

Petrosyants, S. P. ;

Ilyukhin, A. B. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (13) :2047-2069

[8] REORIENTATIONAL MOTIONS AND SELF-DIFFUSION OF IONS IN (NH4)3[INF6] AND (NH4)3[GAF6] CRYSTALS AS STUDIED BY H-1 AND F-19 NUCLEAR MAGNETIC-RESONANCE AND ELECTRICAL-CONDUCTIVITY EXPERIMENTS [J].

SASAKI, A ;

FURUKAWA, Y ;

NAKAMURA, D .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1989, 93 (10) :1142-1147

[9] 115In and 19F MAS NMR study of (NH4)3InF6 phases [J].

Scholz, G. ;

Krahl, T. ;

Ahrens, M. ;

Martineau, C. ;

Buzare, J. Y. ;

Jaeger, C. ;

Kemnitz, E. .

JOURNAL OF FLUORINE CHEMISTRY, 2011, 132 (04) :244-249

[10]

Sheldrick G.M., 2000, SHELXTL

← 1 2 →