CRYSTAL STRUCTURE OF NEW AMMONIUM FLUOROINDATE(III) (NH4)2[InF5]

被引:4
作者
Davidovich, R. L. [1 ]
Logvinova, V. B. [1 ]
Tkachev, V. V. [2 ]
Shilov, G. V. [2 ]
机构
[1] Russian Acad Sci, Far Eastern Branch, Inst Chem, Vladivostok, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka, Russia
关键词
synthesis; indium(III); complex fluoride; ammonium; octahedron; polymer chain; crystal structure; INDIUM FLUORIDE;
D O I
10.1134/S0022476617030192
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new indium(III) fluoride complex with the ammonium cation (NH4)(2)[InF5] is synthesized and its crystal structure is studied. The structure of (NH4)(2)[InF5] is formed of NH4+ cations and complex [InF5](2-) anions. The In atom in the complex anion surrounded by four terminal and two bridging F atoms forms an almost regular octahedral coordination polyhedron (CN 6) with two terminal F atoms in the axial positions and two terminal and two bridging F atoms in the equatorial plane. Through bridging F atoms, the InF6 polyhedra are arranged in polymer trans- vertex-connected corrugated anion chains (InF5)(n)(2n-) directed along the c axis. The N-H center dot center dot center dot F hydrogen bonds organize the chains in a three-dimensional framework.
引用
收藏
页码:585 / 587
页数:3
相关论文
共 11 条
[1]   THERMAL-DECOMPOSITION OF AMMONIUM HEXAFLUOROGALLATE AND AMMONIUM HEXAFLUOROINDATE - NEW CRYSTALLINE FORMS OF GALLIUM FLUORIDE AND INDIUM FLUORIDE [J].
BECK, LK ;
KUGLER, BH ;
HAENDLER, HM .
JOURNAL OF SOLID STATE CHEMISTRY, 1973, 8 (04) :312-317
[2]   STRUKTUREN DER HEXAFLUOROMETALLATE(III) [J].
BODE, H ;
VOSS, E .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1957, 290 (1-2) :1-16
[3]  
CHAMPARN.JC, 1974, CR ACAD SCI C CHIM, V278, P171
[4]  
Deichman E. N., 1967, ZH NEORG KHIM, V12, P307
[5]   Solvothermal Synthesis and Luminescent Properties of Two Organically Templated Chain-Structure Fluorides, [C4H14N2][MF5] (M = In, Sc) [J].
Jayasundera, Anil C. A. ;
Finch, Adrian A. ;
Wormald, Philip ;
Lightfoot, Philip .
CHEMISTRY OF MATERIALS, 2008, 20 (21) :6810-6815
[6]   Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, β-(NH4)3InF6 and [NH4]3[C6H21N4]2[In4F21] [J].
Jayasundera, Anil C. A. ;
Goff, Richard J. ;
Li, Yang ;
Finch, Adrian A. ;
Lightfoot, Philip .
JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (02) :356-360
[7]   Indium(III) Coordination Compounds [J].
Petrosyants, S. P. ;
Ilyukhin, A. B. .
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (13) :2047-2069
[8]   REORIENTATIONAL MOTIONS AND SELF-DIFFUSION OF IONS IN (NH4)3[INF6] AND (NH4)3[GAF6] CRYSTALS AS STUDIED BY H-1 AND F-19 NUCLEAR MAGNETIC-RESONANCE AND ELECTRICAL-CONDUCTIVITY EXPERIMENTS [J].
SASAKI, A ;
FURUKAWA, Y ;
NAKAMURA, D .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1989, 93 (10) :1142-1147
[9]   115In and 19F MAS NMR study of (NH4)3InF6 phases [J].
Scholz, G. ;
Krahl, T. ;
Ahrens, M. ;
Martineau, C. ;
Buzare, J. Y. ;
Jaeger, C. ;
Kemnitz, E. .
JOURNAL OF FLUORINE CHEMISTRY, 2011, 132 (04) :244-249
[10]  
Sheldrick G.M., 2000, SHELXTL