Crystal structure of theUO2SO4 • 2SO(CH3)2 compound:: A new type of uranyl sulfate ribbons and the UO2SO4 • 2SO (CH3)2-UO2SO4 • 2CO(NH2)2 morphotropic transition

被引：1
|
作者：
Alekseev, E. V.
Suleimanov, E. V.
Chuprunov, E. V.
Fukin, G. K.
Baranov, E. V.
机构：
[1] Nizhnii Novgorod State Univ, Nizhnii Novgorod 603950, Russia
[2] Russian Acad Sci, Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603950, Russia
来源：
CRYSTALLOGRAPHY REPORTS | 2007年 / 52卷 / 02期
关键词：
61.66.-f;
D O I：
10.1134/S1063774507020174
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Single crystals of bis(dimethyl sulfoxide) uranyl sulfate are prepared, and their crystal structure is determined using X-ray diffraction analysis. The crystals are monoclinic, space group P2(1)/c, a = 12.9189(8) angstrom, b = 7.9008(5) angstrom, c = 12.1405(7) angstrom, beta = 95.677(1)degrees, R-1 = 0.0216, wR(2) = 0.0468 for 2761 unique reflections with F > 2 sigma(F). The crystal structure of the UO2SO4 center dot 2Dmso compound (where Dmso is dimethyl sulfoxide) is built up of infinite uncharged ribbons of the composition [UO2SO4 center dot 2Dmso](infinity), in which the SO4 tetrahedron is tridentately coordinated to two uranyl groups. The differences between the structures of the uranyl sulfate compounds formed upon replacement of dimethyl sulfoxide by other molecules are considered.
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页码：266 / 270
页数：5
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