Synthesis and Characterization of γ-Fe2O3@HAp@β-CD Core-Shell Nanoparticles As a Novel Magnetic Nanoreactor and Its Application in the One-Pot Preparation of β-azido Alcohols, β-nitro Alcohols, and β-cyanohydrins

被引：0

作者：

Khosravinia, Sara ^{[1
]}

Kiasat, Ali Reza ^{[1
]}

Saghanezhad, Seyyed Jafar ^{[2
]}

机构：

[1] Shahid Chamran Univ, Coll Sci, Chem Dept, Ahvaz 6135743169, Iran

[2] ACECR Prod Technol Res Inst, Ahvaz, Iran

来源：

IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION | 2019年 / 38卷 / 03期

关键词：

Hydroxyapatite-encapsulated-gamma-Fe2O3; beta-cyclodextrin; Epoxides; beta-azido alcohols; beta-nitro alcohols; beta-cyanohydrins; PHASE-TRANSFER CATALYST; CYCLODEXTRIN; EPOXIDES; SILICA; IMMOBILIZATION; NANOCOMPOSITE; MICROVESSEL; WATER; GEL;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, beta-cyclodextrin(beta-CD) supported, hydroxyapatite encapsulated gamma-Fe2O3(gamma-Fe2O3@HAp@beta-CD) was successfully prepared and evaluated as a solid-liquid phase transfer catalyst and also a molecular host system and nanoreactor for the nucleophilic ring opening of epoxides in water for the preparation of beta-azido alcohols, beta-nitro alcohols, and beta-cyanohydrins. The catalyst was characterized with FT-IR, XRD, TGA and SEM. This procedure offers several advantages including excellent regioselectivity, high yields, short reaction times, recyclable catalyst, easy separation of the catalyst through external magnet, and easy work-up.

引用

页码：61 / 68

页数：8

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