Low GWP halocarbon refrigerants: A review of thermophysical properties

被引:151
作者
Bobbo, Sergio [1 ]
Di Nicola, Giovanni [2 ]
Zilio, Claudio [3 ]
Brown, J. Steven [4 ]
Fedele, Laura [1 ]
机构
[1] CNR, Ist Tecnol Costruz, Corso Stati Uniti 4, I-35131 Padua, Italy
[2] Univ Politech Marche, Dipartimento Ingn Ind & Sci Matemat, I-60131 Ancona, Italy
[3] Univ Padua, Dipartimento Tecn & Gest Sistemi Ind, I-36100 Vicenza, Italy
[4] Catholic Univ Amer, Dept Mech Engn, Washington, DC 20064 USA
来源
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID | 2018年 / 90卷
关键词
HCFO; HFO; Low GWP; Refrigerants; Thermophysical properties; Experimental data; VAPOR-LIQUID-EQUILIBRIUM; SATURATED PRESSURE MEASUREMENTS; ISOBARIC HEAT-CAPACITY; RHO-T PROPERTY; BUBBLE POINT PRESSURE; GASEOUS PVT PROPERTY; BINARY-MIXTURES; THERMODYNAMIC PROPERTIES; 2,3,3,3-TETRAFLUOROPROP-1-ENE R1234YF; DENSITY-MEASUREMENTS;
D O I
10.1016/j.ijrefrig.2018.03.027
中图分类号
O414.1 [热力学];
学科分类号
摘要
In the present work, a large number of compounds described in the publicly available literature have been reviewed with the aim to identify possible substitutes for high-GWP HFCs in HVAC&R and organic Rankine cycle (ORC) applications. Taking into account various criteria (particularly low toxicity, low flammability, low GWP, and high energy efficiency), only a few single-component compounds are suitable for many of the relevant applications. In particular, in addition to natural fluids, studies have shown that there are only a few HFCs and a dozen or so HFOs, i. e. halogenated olefins characterized by the presence of a C = C double bond in the molecule, that are potentially suitable for a number of relevant applications. Here, a review of the present state-of-the-art of experimentally-determined thermophysical properties of a number of HFOs working fluids and their mixtures also with other categories of refrigerants is presented, with particular emphasis placed on saturation and critical properties, vapor phase PVT data, liquid density, specific heat capacity, thermal conductivity, viscosity, and surface tension. (C) 2018 Elsevier Ltd and IIR. All rights reserved.
引用
收藏
页码:181 / 201
页数:21
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