Trinuclear iodobismuthate complex [Na3(Me2CO)12][Bi3I12]: Synthesis and crystal structure

被引：19

作者：

Adonin, S. A. ^{[1
,2
]}

Peresypkina, E. V. ^{[1
,2
]}

Sokolov, M. N. ^{[1
,2
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2014年 / 40卷 / 12期

关键词：

AMMONIUM; HYBRIDS; IODIDE; CATION;

D O I：

10.1134/S107032841412001X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of BiI3 and NaI in acetone gives a trinuclear iodobismuthate complex, [Na-3(Me2CO)(12)][Bi3I12] (I), which was studied by X-ray diffraction (CIF file CCDC no. 996330). The centrosymmetric [Bi (3) (III) I-12](3-) anions are groups of three distorted {BiI6} octahedra coupled at the faces. The sodium cations combine six Me2CO molecules in the bidentate bridging mode to give linear trimers in which the side sodium ions coordinate six terminal acetone molecules.

引用

页码：867 / 870

页数：4

共 24 条

[1] [PtBi2I12]2-: the first polyiodobismuthate containing an octahedral heterometallic unit [J].

Adonin, Sergey A. ;

Sokolov, Maxim N. ;

Smolentsev, Anton I. ;

Kozlova, Svetlana G. ;

Fedin, Vladimir P. .

DALTON TRANSACTIONS, 2013, 42 (27) :9818-9821

[2] Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation [J].

Bi, Wenhua ;

Mercier, Nicolas .

CHEMICAL COMMUNICATIONS, 2008, (44) :5743-5745

[3]

Bruker, 2003, SHELXTL VERS 6 22

[4]

CARMALT CJ, 1995, Z NATURFORSCH B, V50, P1591

[5] STRUCTURAL STUDIES ON SOME IODOANTIMONATE AND IODOBISMUTHATE ANIONS [J].

CARMALT, CJ ;

FARRUGIA, LJ ;

NORMAN, NC .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (01) :47-56

[6] 1D vs 2D crystal architecture of hybrid inorganic-organic structures with benzidine dication [J].

Dobrzycki, Lukasz ;

Wozniak, Krzysztof .

JOURNAL OF MOLECULAR STRUCTURE, 2009, 921 (1-3) :18-33

[7] Syntheses and crystal structures of several novel alkylammonium iodobismuthate materials containing the 1,3-bis-(4-piperidinium)propane cation [J].

Goforth, AM ;

Peterson, L ;

Smith, MD ;

zur Loye, HC .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (11) :3529-3540

[8] [Ru(2,2′-bipy)3]2[Bi4I16]:: A bimetallic inorganic-organic complex consisting of a d-metal coordination cation and a polynuclear iodobismuthate anion [J].

Goforth, AM ;

Gardinier, JR ;

Smith, MD ;

Peterson, L ;

Loye, HCZ .

INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (08) :684-688

[9] Structural Diversity and Thermochromic Properties of Iodobismuthate Materials Containing d-Metal Coordination Cations: Observation of a High Symmetry [Bi3I11]2- Anion and of Isolated I- Anions [J].

Goforth, Andrea M. ;

Tershansy, Meredith A. ;

Smith, Mark D. ;

Peterson, LeRoy, Jr. ;

Kelley, Jennifer G. ;

DeBenedetti, William J. I. ;

zur Loye, Hans-Conrad .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (03) :603-612

[10] SYNTHESIS AND CRYSTAL-STRUCTURE OF [LI(THF)4]2[BI4I14(THF)2], [LI(THF)4]4[BI5I19], AND (PH4P)4[BI6I22] [J].

KRAUTSCHEID, H .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (09) :1559-1564

← 1 2 3 →