Isolation and structural characterization of a polyhydrido lanthanide cluster complex consisting of "(C5Me4SiMe3)LuH2" units

被引：116

作者：

Tardif, O ^{[1
]}

Nishiura, M ^{[1
]}

Hou, ZM ^{[1
]}

机构：

[1] RIKEN, Inst Phys & Chem Res, Organomet Chem Lab, Wako, Saitama 3510198, Japan

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 06期

关键词：

D O I：

10.1021/om021014b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the mixed alkyl / hydride complex [Cp'Lu(CH2SiMe3)(mu-H)(THF)](2) (2; CP'= C3Me4SiMe3) with 1 equiv of PhSiH3 (per Lu) in benzene or OEt2 afforded the polyhydrido cluster [Cp'LuH2](4) (3), while hydrogenolysis of 2 with H-2 (1 atm) in THF yielded the THF-coordinated complex [Cp'Lu(mu-H)(2)](4)(THF) (4). Complexes 3 and 4 are interconvertible, without decomposition or ligand redistribution.

引用

页码：1171 / 1173

页数：3

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