Isolation and structural characterization of a polyhydrido lanthanide cluster complex consisting of "(C5Me4SiMe3)LuH2" units

被引：116
|
作者：
Tardif, O [1 ]
Nishiura, M [1 ]
Hou, ZM [1 ]
机构：
[1] RIKEN, Inst Phys & Chem Res, Organomet Chem Lab, Wako, Saitama 3510198, Japan
来源：
ORGANOMETALLICS | 2003年 / 22卷 / 06期
关键词：
D O I：
10.1021/om021014b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of the mixed alkyl / hydride complex [Cp'Lu(CH2SiMe3)(mu-H)(THF)](2) (2; CP'= C3Me4SiMe3) with 1 equiv of PhSiH3 (per Lu) in benzene or OEt2 afforded the polyhydrido cluster [Cp'LuH2](4) (3), while hydrogenolysis of 2 with H-2 (1 atm) in THF yielded the THF-coordinated complex [Cp'Lu(mu-H)(2)](4)(THF) (4). Complexes 3 and 4 are interconvertible, without decomposition or ligand redistribution.
引用
收藏
页码：1171 / 1173
页数：3
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