Synthesis and characterization of (5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-dieno) nickel bis(O,O′'-dialkyldithiophosphate)

被引：0

作者：

Xie, B ^{[1
]}

Wu, SY

机构：

[1] Sichuan Inst Light Ind & Chem Technol, Dept Basic Sci, Zigong 643033, Peoples R China

[2] Sichuan Inst Light Ind & Chem Technol, Dept Light Ind, Zigong 643033, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1998年 / 19卷 / 01期

关键词：

tetraazamacrocycle; O; '-dialkyldithiophosphate; coordination; configuration;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four nickel complexes [Ni(hmtade) {SSP(OR)(2)}(2)] (hmtade = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene; R = phenyl, 2-naphthyl, 2-phenylethyl and cyclohexyl) were synthesized and characterized by elemental analysis, molar conductivity, infrared spectra, electronic spectra, NMR spectra (H-1 and P-31) and TG-DTA analysis. The results indicate that all complexes are non-electrolysis in DMSO and O,O'-dialkyldithiophosphoric acid radicals as monodentate ligands coordinate to nickel atom. The tetraazamacrocyclic configuration and the TG-DTA curves of complexes are also discussed.

引用

页码：74 / 77

页数：4

共 12 条

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