The nine modes of complexed water

被引：10

作者：

Parker, SF ^{[1
]}

Shankland, K

Sprunt, JC

Jayasooriya, UA

机构：

[1] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England

[2] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1997年 / 53卷 / 13期

关键词：

FT-Raman; infrared; inelastic neutron spectroscopy; water;

D O I：

10.1016/S1386-1425(97)00173-X

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

From a combination of FT-Raman, infrared and inelastic neutron spectroscopies, all of the internal and librational modes of complexed water have been assigned unambiguously. Two of the translational modes (Fe-O stretch and Fe-O bend) have been assigned and the evidence suggests that the remaining mode (an Fe-O bend) is coincident with the other bend. The spectra provide good evidence that the FE-OH2 twist is highly anharmonic and that the hydrogen bonding has a major effect on the Fe-O dynamics. (C) 1997 Elsevier Science B.V.

引用

页码：2333 / 2339

页数：7

共 15 条

[1] SINGLE-CRYSTAL RAMAN STUDY OF SOME AQUO-PENTACHLORO-SALTS [MCI5-(H2O)]2- (M = IN OR FE) [J].

ADAMS, DM ;

NEWTON, DC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (05) :681-&

[2] SURVEY STUDY OF VIBRATIONAL SPECTRA OF SOME AQUO-HALOGENO-COMPLEXES [J].

ADAMS, DM ;

LOCK, PJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (17) :2801-&

[3] STUDY OF LOW-FREQUENCY MOTIONS IN POLYETHYLENE + PARAFFIN HYDROCARBONS BY NEUTRON INELASTIC SCATTERING [J].

DANNER, HR ;

BERGER, M ;

SAFFORD, GJ ;

BOUTIN, H .

JOURNAL OF CHEMICAL PHYSICS, 1964, 40 (05) :1417-&

[4] INFRARED STUDIES OF WATER IN CRYSTALLINE HYDRATES - K2FECL5.H2O (ERYTHROSIDERITE) AND RELATED AQUOPENTACHLOROFERRATES(III) [J].

FALK, M ;

HUANG, CH ;

KNOP, O .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (01) :51-57

[5]

Fateley W.G., 1972, INFRARED RAMAN SELEC

[6] A REVIEW OF THE ANALYSIS OF MOLECULAR VIBRATIONS USING INS [J].

KEARLEY, GJ .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 1995, 354 (01) :53-58

[7] A PROFILE-REFINEMENT APPROACH FOR NORMAL-COORDINATE ANALYSES OF INELASTIC NEUTRON-SCATTERING SPECTRA [J].

KEARLEY, GJ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1986, 82 :41-48

[8]

PARKER SF, 1994, SPECTROSC EUR, V6, P14

[9]

Penfold J., 1986, RAL86019 TFXA

[10] NEUTRON-SCATTERING STUDY OF MOTIONS OF WATER MOLECULES IN HYDRATED SALTS OF TRANSITION METALS [J].

RUSH, JJ ;

FERRARO, JR ;

WALKER, A .

INORGANIC CHEMISTRY, 1967, 6 (02) :346-&

← 1 2 →