Printable Skin-Driven Mechanoluminescence Devices via Nanodoped Matrix Modification

被引:239
作者
Qian, Xin [1 ,2 ]
Cai, Zheren [1 ,2 ]
Su, Meng [1 ]
Li, Fengyu [1 ]
Fang, Wei [3 ,4 ]
Li, Yudong [1 ]
Zhou, Xue [1 ]
Li, Qunyang [3 ,5 ]
Feng, Xiqiao [3 ,4 ]
Li, Wenbo [1 ]
Hu, Xiaotian [1 ,2 ]
Wang, Xiandi [6 ]
Pan, Caofeng [6 ]
Song, Yanlin [1 ]
机构
[1] Chinese Acad Sci ICCAS, Beijing Engn Res Ctr Nanomat Green Printing Techn, CAS Res Educ Ctr Excellence Mol Sci,Inst Chem, Natl Lab Mol Sci BNLMS,Key Lab Green Printing, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Tsinghua Univ, AML, Dept Engn Mech, Beijing 100084, Peoples R China
[4] Tsinghua Univ, Inst Biomech & Med Engn, Dept Engn Mech, Beijing 100084, Peoples R China
[5] Tsinghua Univ, Ctr Nano & Micro Mech, Beijing 100084, Peoples R China
[6] Chinese Acad Sci, Beijing Inst Nanoenergy & Nanosyst, Beijing 100083, Peoples R China
关键词
direct writing; matrix manipulation; mechanoluminescence; nano-/microdopant; photonic skin; PARTICLE-SIZE; IN-VIVO; PRESSURE; NANOPARTICLE; ADHESION; FILMS;
D O I
10.1002/adma.201800291
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mechanically driven light generation is an exciting and under-exploited phenomenon with a variety of possible practical applications. However, the current driving mode of mechanoluminescence (ML) devices needs strong stimuli. Here, a flexible sensitive ML device via nanodopant elasticity modulus modification is introduced. Rigid ZnS:M2+ (Mn/Cu)@Al2O3 microparticles are dispersed into soft poly(dimethylsiloxane) (PDMS) film and printed out to form flexible devices. For various flexible and sensitive scenes, SiO2 nanoparticles are adopted to adjust the elasticity modulus of the PDMS matrix. The doped nanoparticles can concentrate stress to ZnS:M2+ (Mn/Cu)@Al2O3 microparticles and achieve intense ML under weak stimuli of the moving skin. The printed nano-/microparticle-doped matrix film can achieve skin-driven ML, which can be adopted to present fetching augmented animations expressions. The printable ML film, amenable to large areas, low-cost manufacturing, and mechanical softness will be versatile on stress visualization, luminescent sensors, and open definitely new functional skin with novel augmented animations expressions, the photonic skin.
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页数:6
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