Nucleophilic Substitution Reactions at Vinylic Carbons

被引：1

作者：

Shen, Shusu ^{[1
]}

机构：

[1] Suzhou Univ Sci & Technol, Ctr Separat & Purificat Mat & Technol, Suzhou 215009, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 34卷 / 12期

关键词：

vinylic carbon; sp(2) carbon; nucleophilic substitution reaction; sp(2) nitrogen; INTRAMOLECULAR CYCLIZATION; O-METHYLSULFONYLOXIMES; ETHYLENIC DERIVATIVES; S(N)2 SUBSTITUTION; SP(2) CARBON; INVERSION; CONFIGURATION; HALIDES; QUINOLINES; TETRAHYDROPYRIDINES;

D O I：

10.6023/cjoc201406046

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The recently research progress in the nucleophilic substitution reactions at the sp(2)-carbons, mainly at the vinylic carbons is reviewed. The theoretical studies on the nucleophilic substitution reactions at the vinylic carbons, and their applications in organic synthesis, especially in the synthesis of heterocycle compounds, are illustrated. And, researches and applications of the nucleophilic substitution reactions at other unsaturated atoms like sp(2) nitrogens are also discussed.

引用

页码：2448 / 2455

页数：8

共 45 条

[41]

Terrier F, 2013, MODERN NUCLEOPHILIC AROMATIC SUBSTITUTION, P1, DOI 10.1002/9783527656141

[42] NEW SYNTHESIS OF VINYL SELENIDES NUCLEOPHILIC SUBSTITUTIONS OF UNACTIVATED VINYL HALIDES BY SELENIDE ANIONS [J].