Four metal-organic networks based on benzene-1,4-dioxyacetic acid and dipyrido[3,2-a:2′,3′-c]phenazine ligand

被引：38
作者：
Li, Xiuying [2 ]
Liu, Chunbo [1 ,3 ]
Che, Guangbo [1 ,3 ]
Wang, Xiangcheng [1 ]
Li, Chunxiang [1 ]
Yan, Yongsheng [1 ]
Guan, Qingfeng [2 ]
机构：
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
[2] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
[3] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 07期
关键词：
Benzene-1,4-dioxyacetic acid; Dipyrido[3,2-a:2 ',3 '-c]phenazine; pi-pi Interactions; Transition metals; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESIS; MAGNETIC-PROPERTIES; PI-STACKING; COMPLEXES; FRAMEWORKS; CLUSTERS; SERIES; 3D;
D O I：
10.1016/j.ica.2009.12.056
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four structurally diverse complexes, [Cd(dppz)(bdoa)](n) (1), [Zn(dppz)(bdoa)(H(2)O)](n) (2), [Fe(dppz)(2)(b-doa)](n)center dot 2nH(2)O (3), and [Co(2)(dppz)(2)(bdoa)(2)(H(2)O)](n)center dot 3nH(2)O (4), where H(2)bdoa = benzene-1,4-dioxyacetic acid and dppz = dipyrido[3,2-a:2',3'-c]phenazine, have been hydrothermally synthesized. Compounds 1-4 feature chain structures. There exist pi-pi interactions in the structures of 1, 2 and 4. Two neighboring chains of 1 are linked through the pi-pi interactions into a double chain supramolecular structure. The chains of 2 and 4 are further extended by the pi-pi interactions to form 3D and 2D supramolecular structures, respectively. The structural differences among such complexes show that the transition metals have important influences on their structures. The photoluminescent property of complex 2 and the magnetic property of complex 4 have also been investigated. (C) 2010 Elsevier B.V. All rights reserved.
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页码：1359 / 1366
页数：8
相关论文
共 36 条
[1]   Octanuclear zinc(II) and cobalt(II) clusters produced by cooperative tetrameric assembling of oxime chelate ligands [J].
Akine, Shigehisa ;
Dong, Wenkui ;
Nabeshima, Tatsuya .
INORGANIC CHEMISTRY, 2006, 45 (12) :4677-4684
[2]  
[Anonymous], 1997, SHELXL 97 PROGRAMS X
[3]  
BETTINA B, 2008, EUR J INORG CHEM, P1632
[4]  
Burrows AD, 2003, EUR J INORG CHEM, P766
[5]   Syntheses, structures and photoluminescence of a series of metal-organic complexes with 1,3,5-benzenetricarboxylate and pyrazino[2,3-f][1,10]-phenanthroline ligands [J].
Che, Guang-Bo ;
Liu, Chun-Bo ;
Liu, Bo ;
Wang, Qing-Wei ;
Xu, Zhan-Lin .
CRYSTENGCOMM, 2008, 10 (02) :184-191
[6]   Hydrothermal syntheses of some derivatives of tetraazatriphenylene [J].
Che, Guangbo ;
Li, Wenlian ;
Kong, Zhiguo ;
Su, Zisheng ;
Chu, Bei ;
Li, Bin ;
Zhang, Zhiqiang ;
Hu, Zhizhi ;
Chi, Haijun .
SYNTHETIC COMMUNICATIONS, 2006, 36 (17) :2519-2524
[7]   Syntheses, structures and photoluminescence properties of a series of metal-organic complexes with 1,3-benzenedicarboxylate and 10,11,12,13-tetrahydro-4,5,9,14-tetraaza-benzo[b]triphenylene ligands [J].
Che, Guangbo ;
Wang, Jian ;
Liu, Chunbo ;
Li, Xiuying ;
Liu, Bo ;
Sun, Jun ;
Liu, Yang ;
Lua, Lu .
INORGANICA CHIMICA ACTA, 2009, 362 (08) :2756-2761
[8]   Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates [J].
Chen, W ;
Wang, JY ;
Chen, C ;
Yue, Q ;
Yuan, HM ;
Chen, JS ;
Wang, SN .
INORGANIC CHEMISTRY, 2003, 42 (04) :944-946
[9]   A novel ribbon-candy-like supramolecular architecture of cadmium(II)-terephthalate polymer with giant rhombic channels:: twofold interpenetration of the 3D 8210-a net [J].
Dai, JC ;
Wu, XT ;
Fu, ZY ;
Hu, SM ;
Du, WX ;
Cui, CP ;
Wu, LM ;
Zhang, HH ;
Sun, RQ .
CHEMICAL COMMUNICATIONS, 2002, (01) :12-13
[10]   Synthesis and characterization of new coordination polymers generated from bent bis(cyanophenyl)oxadiazole ligands and Ag(I) salts [J].
Dong, YB ;
Wang, HY ;
Ma, JP ;
Shen, DZ ;
Huang, RQ .
INORGANIC CHEMISTRY, 2005, 44 (13) :4679-4692
1234