Insights into the deactivation of neutral nickel ethylene polymerization catalysts in the presence of functionalized olefins

被引：60

作者：

Waltman, AW ^{[1
]}

Younkin, TR ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 22期

关键词：

D O I：

10.1021/om049360b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A study on the products of reaction between a neutral nickel(II) olefin polymerization catalyst and methyl acrylate is presented. A deactivation mechanism involving hydrogen transfer from substrate to catalyst is suggested.

引用

页码：5121 / 5123

页数：3

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