Production of isoamyl propionate: use of Amberlyst-15 in batch reactor and packed bed reactor

被引:8
作者
Bhandare, Rajendra B. [1 ]
Katariya, Amit [2 ]
Mahajan, Yogesh S. [1 ]
机构
[1] Dr BA Technol Univ, Chem Engn Dept, Lonere, Maharashtra, India
[2] Amusavi MTC Private Ltd, Pune, Maharashtra, India
关键词
Esterification; propionic acid; isoamyl alcohol; Amberlyst-15; N-AMYL ALCOHOL; ACETIC-ACID; MEMBRANE REACTORS; PERVAPORATION; ESTERIFICATION; KINETICS; DISTILLATION; METHANOL; ACETATE; CHROMATOGRAPHY;
D O I
10.1080/02533839.2021.1933597
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The synthesis of isoamyl propionate by esterification of propionic acid with isoamyl alcohol is presented in this work using ion exchange resin Amberlyst-15. In batch kinetics, about 33% conversion of acid was obtained in 3 hours under the conditions such as temperature of 343 K, 1:3 molar ratio, Amberlyst-15 catalyst with 5% loading (w/w of limiting component). For enhancing the performance of the reaction and to make the process continuous, the reaction was conducted in a packed bed reactor. Conversion of 53% was obtained in 3 hours, thus indicating the possibility of process intensification.
引用
收藏
页码:509 / 518
页数:10
相关论文
共 40 条
  • [1] SELF-CONDENSATION OF CYCLOHEXANONE CATALYZED BY AMBERLYST .15. STUDY OF DIFFUSIONAL RESISTANCES AND DEACTIVATION OF THE CATALYST
    ARAGON, JM
    VEGAS, JMR
    JODRA, LG
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (03) : 592 - 599
  • [2] CATIONIC ION-EXCHANGE RESINS AS CATALYST
    CHAKRABARTI, A
    SHARMA, MM
    [J]. REACTIVE POLYMERS, 1993, 20 (1-2): : 1 - 45
  • [3] Chandane V.S., 2016, RESOUR EFFIC TECHNOL, V2, pS47, DOI DOI 10.1016/J.REFFIT.2016.10.008
  • [4] Process optimization and kinetic modeling for esterification of propionic acid with benzyl alcohol on ion-exchange resin catalyst
    Chandane, Vishal Suresh
    Rathod, Ajit Pralhad
    Wasewar, Kailas Lachchhuram
    Sonawane, Shriram Shaligram
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2017, 34 (04) : 987 - 996
  • [5] Esterification of propionic acid with isopropyl alcohol over ion exchange resins: Optimization and kinetics
    Chandane, Vishal Suresh
    Rathod, Ajit Pralhad
    Wasewar, Kailas Lachchhuram
    Sonawane, Shriram Shaligram
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2017, 34 (01) : 249 - 258
  • [6] Kinetics of esterification of propionic acid with n-amyl alcohol in the presence of cation exchange resins
    Erdem, Beyhan
    Cebe, Mustafa
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2006, 23 (06) : 896 - 901
  • [7] Fogler H.S., 2016, ELEMENTS CHEM REACTI
  • [8] Reactive chromatography for the synthesis of 2-ethylhexyl acetate
    Gyani, Vivek Chandra
    Mahajani, Sanjay
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 2008, 43 (9-10) : 2245 - 2268
  • [9] Industrial Applications of Reactive Distillation: Recent Trends
    Hiwale, Rameshwar S.
    Bhate, NitinV.
    Mahajan, Yogesh S.
    Mahajani, Sanjay M.
    [J]. INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2004, 2
  • [10] REACTIVE EXTRACTION OF PROPIONIC ACID USING TRI-n-OCTYLAMINE
    Keshav, Amit
    Wasewar, Kailas L.
    Chand, Shri
    [J]. CHEMICAL ENGINEERING COMMUNICATIONS, 2010, 197 (04) : 606 - 626