Peroxide/Potassium Iodide Redox Systems for in situ Oxyiodination of Organic Compounds under Liquid-Phase and Solvent-Free Conditions

被引：3

作者：

Venkateshwarlu, Gattu ^{[1
]}

Premalatha, Akarapu ^{[1
]}

Chakradhar, Anuganti ^{[1
]}

Rajanna, Kamatala Chinna ^{[1
]}

Prakash, Pondichery Kuppuswamy Sai ^{[1
]}

机构：

[1] Osmania Univ, Dept Chem, Hyderabad 500007, Andhra Pradesh, India

来源：

HELVETICA CHIMICA ACTA | 2010年 / 93卷 / 02期

关键词：

CROSS-COUPLING REACTION; N-BROMOSUCCINIMIDE; REGIOSELECTIVE IODINATION; OXIDATIVE BROMINATION; MILD; REAGENT; PHENOLS; ARENES; HALOGENATION; ALCOHOLS;

D O I：

10.1002/hlca.200900188

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iodination of certain aromatic amines and phenols are triggered by the oxidation of K1 by peroxy compounds such as tert-butyl hydroperoxide ('BuOOH) under liquid-phase and solvent-free conditions by grinding the reactants in a mortar with a pestle. The reactions afforded corresponding iodo derivatives in good yield with high regioselectivity (Table 1).

引用

页码：345 / 349

页数：5

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