Chromium(VI) removal by tri-n-octylamine/n-heptane via a pseudo-emulsion-based hollow fiber strip dispersion technique
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作者:
Wang, Yuchen
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机构:
Harbin Inst Technol, Sch Municipal & Environm Engn, Harbin, Peoples R ChinaHarbin Inst Technol, Sch Municipal & Environm Engn, Harbin, Peoples R China
Wang, Yuchen
[1
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Li, Yingxue
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机构:
Changzhou Vocat Inst Engn, Inst Pharmaceut & Environm Engn, Changzhou, Peoples R ChinaHarbin Inst Technol, Sch Municipal & Environm Engn, Harbin, Peoples R China
Li, Yingxue
[2
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Zhong, Yijian
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Guilin Univ Technol, Coll Environm Sci & Engn, Guilin, Peoples R ChinaHarbin Inst Technol, Sch Municipal & Environm Engn, Harbin, Peoples R China
Zhong, Yijian
[3
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Cui, Chongwei
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Harbin Inst Technol, Sch Municipal & Environm Engn, Harbin, Peoples R ChinaHarbin Inst Technol, Sch Municipal & Environm Engn, Harbin, Peoples R China
Cui, Chongwei
[1
]
机构:
[1] Harbin Inst Technol, Sch Municipal & Environm Engn, Harbin, Peoples R China
[2] Changzhou Vocat Inst Engn, Inst Pharmaceut & Environm Engn, Changzhou, Peoples R China
[3] Guilin Univ Technol, Coll Environm Sci & Engn, Guilin, Peoples R China
Transport of Cr(VI) from acidic media via a pseudo-emulsion-based hollow fiber strip dispersion (PEHFSD) technique using tri-n-octylamine (N235) dissolved in n-heptane was investigated. The effects of various hydrodynamic and chemical parameters, including the flow rates, variation in feed pH, initial Cr(VI) concentration, and N235 concentration in the pseudo-emulsion, on Cr(VI) permeation were analyzed. The optimum conditions for Cr(VI) separation from hydrochloric acidic media were also estimated. The analysis of Cr(VI) transport was made on the basis of the overall mass-transfer coefficient of permeation; the resistances of mass transfer were also evaluated. The results indicated that the ion transport is controlled by the diffusion of Cr(VI) species in the stagnant film between the aqueous solution and the membrane liquid.