Azoporphyrin: The porphyrin analogne of azobenzene

被引：69

作者：

Esdaile, Louisa J.

Jensen, Paul

McMurtrie, John C.

Arnold, Dennis P.

机构：

[1] Queensland Univ Technol, Sch Phys & Chem Sci, Brisbane, Qld 4001, Australia

[2] Univ Sydney, Sch Chem, Crystal Struct Anal Facil, Sydney, NSW 2006, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期

关键词：

absorption spectroscopy; azo compounds; conjugation; macrocycles; porphyrinoids;

D O I：

10.1002/anie.200604658

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Excellent conjugation: The novel azoporphyrins (1,2-bis(porphyrinyl)diazenes) have been prepared by using copper-catalyzed coupling of primary amines. The structure of the azo(triphenylporphyrin) was determined by X-ray crystallography (see picture). The azo linker provides an excellent conjugating pathway for expansion of porphyrin π conjugation. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2090 / 2093

页数：4

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