Azoporphyrin: The porphyrin analogne of azobenzene

被引：67
作者：
Esdaile, Louisa J.
Jensen, Paul
McMurtrie, John C.
Arnold, Dennis P.
机构：
[1] Queensland Univ Technol, Sch Phys & Chem Sci, Brisbane, Qld 4001, Australia
[2] Univ Sydney, Sch Chem, Crystal Struct Anal Facil, Sydney, NSW 2006, Australia
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期
关键词：
absorption spectroscopy; azo compounds; conjugation; macrocycles; porphyrinoids;
D O I：
10.1002/anie.200604658
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Excellent conjugation: The novel azoporphyrins (1,2-bis(porphyrinyl)diazenes) have been prepared by using copper-catalyzed coupling of primary amines. The structure of the azo(triphenylporphyrin) was determined by X-ray crystallography (see picture). The azo linker provides an excellent conjugating pathway for expansion of porphyrin π conjugation. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2090 / 2093
页数：4
相关论文
共 41 条
  • [1] ANDERSON H, COMMUNICATION
  • [2] Arnold DP, 1999, J PORPHYR PHTHALOCYA, V3, P5, DOI 10.1002/(SICI)1099-1409(199901)3:1<5::AID-JPP98>3.0.CO
  • [3] 2-N
  • [4] Preparation of novel highly conjugated bis-porphyrin bridged with a polyene linker
    Blart, E
    Suzenet, F
    Quintard, JP
    Odobel, F
    [J]. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2003, 7 (4-5) : 207 - 213
  • [5] Photoisomerization of azobenzenes and spirocompounds in nematic and in twisted nematic liquid crystals
    Bossi, Mariano L.
    Murgida, Daniel H.
    Aramendia, Pedro F.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (28) : 13804 - 13811
  • [6] Spectral and photophysical properties of ethylene-bridged side-to-side porphyrin dimers .1. Ground-state absorption and fluorescence study and calculation of electronic structure of trans-1,2-bis(meso-octaethylporphyrinyl)ethene
    Chachisvilis, M
    Chirvony, VS
    Shulga, AM
    Kallebring, B
    Larsson, S
    Sundstrom, V
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (32) : 13857 - 13866
  • [7] Photophysical properties of porphyrin tapes
    Cho, HS
    Jeong, DH
    Cho, S
    Kim, D
    Matsuzaki, Y
    Tanaka, K
    Tsuda, A
    Osuka, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (49) : 14642 - 14654
  • [8] EPR STUDY OF OXIDATIVE COUPLING REACTION OF ANILINE HOMOGENEOUSLY CATALYZED BY CU(C5H5N)4(NO3)2
    DEROUANE, EG
    BRAHAM, JN
    HUBIN, R
    [J]. JOURNAL OF CATALYSIS, 1974, 35 (02) : 196 - 201
  • [9] Understanding strong two-photon absorption in π-conjugated porphyrin dimers via double-resonance enhancement in a three-level model
    Drobizhev, M
    Stepanenko, Y
    Dzenis, Y
    Karotki, A
    Rebane, A
    Taylor, PN
    Anderson, HL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (47) : 15352 - 15353
  • [10] OXIDATIONS WITH COPPER-AMINE COMPLEXES .6. OXIDATION OF AROMATIC AMINES AND OF ANILINE IN PARTICULAR
    ENGELSMA, G
    HAVINGA, E
    [J]. TETRAHEDRON, 1958, 2 (3-4) : 289 - 295
12345