An efficient heterogeneous CrOx-Y zeolite catalyst for glucose to HMF conversion in ionic liquids

被引：11

作者：

Aylak, Aziz Rahman ^{[1
]}

Akmaz, Solmaz ^{[1
]}

Koc, Serkan Naci ^{[1
]}

机构：

[1] Istanbul Univ, Dept Chem Engn, Avcilar Campus 34320, Istanbul, Turkey

来源：

PARTICULATE SCIENCE AND TECHNOLOGY | 2017年 / 35卷 / 04期

关键词：

CrCI3; CrOx; HMF; ionic liquids; Y zeolite; SOLID ACID; CELLULOSE; TRANSFORMATION; NANOCATALYSTS; FRUCTOSE; WATER;

D O I：

10.1080/02726351.2016.1168895

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In this study, CrCI3, H-Y, Cr-Y and calcined CrOx-Y zeolites were studied in the liquid phase heterogeneous catalytic conversion of glucose to HMF in ionic liquids. Characterization of catalysts was done in XPS, XRD and NH3-TPD. Both glucose conversion and HMF yield decreased with the addition of chromium (III) chloride impregnated catalysts in comparison to the homogeneous CrCI3-[BMIM]CI system. High glucose and HMF yields were obtained with heterogeneous calcined CrOx-Y zeolite. Best HMF yield achieved was 52.8%.

引用

页码：490 / 493

页数：4

共 22 条

[1] Acid-catalyzed production of 5-hydroxymethyl furfural from D-fructose in subcritical water [J].

Asghari, FS ;

Yoshida, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (07) :2163-2173

[2] Influence of the parent zeolite structure on chromium speciation and catalytic properties of Cr-zeolite catalysts in the ethylene ammoxidation [J].

Ayari, F. ;

Mhamdi, M. ;

Hammedi, T. ;

Alvarez-Rodriguez, J. ;

Guerrero-Ruiz, A. R. ;

Delahay, G. ;

Ghorbel, A. .

APPLIED CATALYSIS A-GENERAL, 2012, 439 :88-100

[3] Oxidative dehydrogenation of propane over chromium-loaded calcium-hydroxyapatite [J].

Boucetta, Charifa ;

Kacimi, Mohamed ;

Ensuque, Alain ;

Piquemal, Jean-Yves ;

Bozon-Verduraz, Francois ;

Ziyad, Mahfoud .

APPLIED CATALYSIS A-GENERAL, 2009, 356 (02) :201-210

[4] Cellulase immobilized mesoporous silica nanocatalysts for efficient cellulose-to-glucose conversion [J].

Chang, Renee Han-Yi ;

Jang, Jen ;

Wu, Kevin C. -W. .

GREEN CHEMISTRY, 2011, 13 (10) :2844-2850

[5] Zeolite-promoted transformation of glucose into 5-hydroxymethylfurfural in ionic liquid [J].

Hu, Lei ;

Wu, Zhen ;

Xu, Jiaxing ;

Sun, Yong ;

Lin, Lu ;

Liu, Shijie .

CHEMICAL ENGINEERING JOURNAL, 2014, 244 :137-144

[6] Efficient conversion of glucose into 5-hydroxymethylfurfural catalyzed by a common Lewis acid SnCl4 in an ionic liquid [J].

Hu, Suqin ;

Zhang, Zhaofu ;

Song, Jinliang ;

Zhou, Yinxi ;

Han, Buxing .

GREEN CHEMISTRY, 2009, 11 (11) :1746-1749

[7] Conversion of D-glucose into 5-hydroxymethylfurfural (HMF) using zeolite in [Bmim]Cl or tetrabutylammonium chloride (TBAC)/CrCl2 [J].

Jadhav, Harishandra ;

Taarning, Esben ;

Pedersen, Christian Marcus ;

Bols, Mikael .

TETRAHEDRON LETTERS, 2012, 53 (08) :983-985

[8] Cellulose-to-HMF conversion using crystalline mesoporous titania and zirconia nanocatalysts in ionic liquid systems [J].

Kuo, I-Jung ;

Suzuki, Norihiro ;

Yamauchi, Yusuke ;

Wu, Kevin C. -W. .

RSC ADVANCES, 2013, 3 (06) :2028-2034

[9]

Lei H., 2013, BIORESOURCE TECHNOLO, V148, P501, DOI [10.1016/j.biortech.2013.09.016, DOI 10.1016/J.BIORTECH.2013.09.016]

[10] Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids [J].

Lima, Sergio ;

Neves, Patricia ;

Antunes, Maria M. ;

Pillinger, Martyn ;

Ignatyev, Nikolai ;

Valente, Anabela A. .

APPLIED CATALYSIS A-GENERAL, 2009, 363 (1-2) :93-99

← 1 2 3 →