Alkene Metathesis for Transformations of Renewables

被引：10

作者：

Bruneau, Christian ^{[1
]}

Fischmeister, Cedric ^{[1
]}

机构：

[1] Univ Rennes, CNRS, ISCR, UMR 6226, Rennes, France

来源：

ORGANOMETALLICS FOR GREEN CATALYSIS | 2019年 / 63卷

关键词：

Fatty acid derivatives; Olefin metathesis; Renewables; Terpenes; RING-CLOSING METATHESIS; FATTY-ACID DERIVATIVES; ACRYLONITRILE CROSS-METATHESIS; HETEROCYCLIC CARBENE LIGANDS; OLEFIN-METATHESIS; METHYL ACRYLATE; RAW-MATERIALS; CATALYTIC CONVERSION; RUTHENIUM CATALYST; EFFICIENT PROTOCOL;

D O I：

10.1007/3418_2018_18

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alkene metathesis of unsaturated bio-sourced olefins, a green and atom economic strategy, has been recently investigated with the objective of producing high-value molecules and polymer precursors. This chapter contains the recent developments in this field using terpenes, terpenoids, and fatty acid derivatives as olefin metathesis partners. The successful achievements with these renewable substrates presenting different types of carbon-carbon double bonds in self-metathesis, ring closing metathesis, cross metathesis including ethenolysis, and ring opening metathesis are presented.

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页码：77 / 102

页数：26

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