Synthesis, structures and properties of cluster complexes [H3O(Ph3PO)3]2[Mo6Cl14] and [H(Ph3PO)2]2[Re6S6Br8]

被引：11

作者：

Kozhomuratova, Zhyidyz S. ^{[1
]}

Mironov, Yuri V. ^{[1
]}

Shestopalov, Michael A. ^{[1
]}

Drebushchak, Irina V. ^{[1
]}

Moroz, Nikolay K. ^{[1
]}

Naumov, Dmitry Y. ^{[1
]}

Smolentsev, Anton I. ^{[1
]}

Uskov, Evgenii M. ^{[1
]}

Fedorov, Vladimir E. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 14期

关键词：

cluster compounds; molybdenum; rhenium; triphenylphosphane oxide; crystal structure; NMR spectroscopy; hydrogen bonding;

D O I：

10.1002/ejic.200601158

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New cluster compounds [H3O(Ph3PO)(3)](2)[Mo6Cl14] (I) and [H(Ph3PO)(2)](2)[Re6S6Br8] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph3PO with octahedral cluster complexes of molybdenum (H3O)(2)Mo6Cl14 center dot 6H(2)O and rhenium K2Re6S6Br8, respectively, (with addition of several drops of HBr). The structures and properties of the products were studied by single-crystal X-ray diffraction and NMR and luminescence spectroscopic methods. The compounds studied are characterized by strong hydrogen bonds with O-O distances of 2.45-2.51 angstrom (I) and 2.34-2.41 angstrom (II); unusual H-bonded cationic trimers, [H3O(Ph3PO)(3)](+), were found in compound I. (c) Wiley-VCH Verlag GmbH & Co.

引用

页码：2055 / 2060

页数：6

共 25 条

[1] NUCLEAR MAGNETIC RESONANCE SPECTRUM FOR ISOSCELES TRIANGULAR CONFIGURATIONS OF NUCLEI [J].

ANDREW, ER ;

FINCH, ND .

PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON SECTION B, 1957, 70 (10) :980-990

[2] NUCLEAR MAGNETIC RESONANCE LINE SHAPE FOR A TRIANGULAR CONFIGURATION OF NUCLEI [J].

ANDREW, ER ;

BERSOHN, R .

JOURNAL OF CHEMICAL PHYSICS, 1950, 18 (02) :159-161

[3]

ANTIPIN MY, 1980, KRISTALLOGRAFIYA+, V25, P514

[4] Solid-state NMR investigations on the nature of hydrogen bonds [J].

Brunner, E ;

Sternberg, U .

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 1998, 32 :21-57

[5] A simple method for the characterization of OHO-hydrogen bonds by 1H-solid state NMR spectroscopy [J].

Emmler, T ;

Gieschler, S ;

Limbach, HH ;

Buntkowsky, G .

JOURNAL OF MOLECULAR STRUCTURE, 2004, 700 (1-3) :29-38

[6] Hexanuclear and higher nuclearity clusters of the Groups 4-7 metals with stabilizing π-donor ligands [J].

Gray, TG .

COORDINATION CHEMISTRY REVIEWS, 2003, 243 (1-2) :213-235

[7] HYDROGEN BONDING IN SOME ADDUCTS OF OXYGEN BASES WITH ACIDS .1. INFRARED SPECTRA AND STRUCTURE OF CRYSTALLINE ADDUCTS OF SOME PHOSPHINE, ARSINE, AND AMINE OXIDES, AND SULPHOXIDES WITH STRONG ACIDS [J].

HADZI, D .

JOURNAL OF THE CHEMICAL SOCIETY, 1962, (DEC) :5128-&

[8] PREPARATION, CRYSTAL AND MOLECULAR-STRUCTURE OF TRIPHENYL-PHOSPHINE-OXIDE HYDROCHLORIDE (C6H5)3PO.HCL [J].

HAUPT, HJ ;

HUBER, F ;

KRUGER, C ;

PREUT, H ;

THIERBACH, D .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 436 (DEC) :229-236

[9] BIS(TRIPHENYLPHOSPHINE OXIDE)HYDRONIUM TETRACHLOROAURATE(III) [J].

JONES, PG ;

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (APR) :1353-1355

[10] Cluster compounds [Ca(DMF)6][Mo6Cl14] and [{Ca(OPPh3)4}{Mo6Cl14}]∞:: Synthesis, crystal structure, and properties [J].

Kozhomuratova, Zh. S. ;

Mironov, Yu. V. ;

Shestopalov, M. A. ;

Gaifulin, Ya. M. ;

Kurat'eva, N. V. ;

Uskov, E. M. ;

Fedorov, V. E. .

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2007, 33 (01) :1-6

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