Synthesis of Styrene Carbonate from Carbon Dioxide and Styrene Oxide with Various Zinc Halide-Based Ionic Liquids

被引：38

作者：

Fujita, Shin-ichiro ^{[1
]}

Nishiura, Masahiro ^{[1
]}

Arai, Masahiko ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Chem Proc Engn, Sapporo, Hokkaido 0608628, Japan

来源：

CATALYSIS LETTERS | 2010年 / 135卷 / 3-4期

关键词：

Styrene carbonate; Styrene oxide; Carbon dioxide; Binary catalyst; Cycloaddition; HIGHLY EFFICIENT CATALYST; CYCLIC CARBONATES; CHEMICAL FIXATION; COUPLING REACTIONS; PROPYLENE CARBONATE; TERMINAL EPOXIDES; CO2; COMPLEXES; CYCLOADDITION; CHLORIDE;

D O I：

10.1007/s10562-010-0286-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Various zinc halide-based ionic liquids were prepared from zinc halides and onium halides as catalysts for the synthesis of styrene carbonate (SC) from styrene oxide and carbon dioxide. The effects of the ionic liquid catalyst composition (types of onium cation and halide, onium cation/zinc ratio) and CO(2) pressure on the reaction were investigated. The effectiveness of the onium cation as the active catalyst component was in the order of tetrabutylammonium > 1-butylpyridinium > 1-butyl-3-methylimidazolium >> choline. The type of halide atom originating from the zinc salt affected the catalytic activity of the ionic liquid more significantly than that of the one originating from the onium salt. The onium cation/zinc ratio also affected the SC yield, but its manner was different depending on the type of onium cation. Influence of CO(2) pressure was not significant.

引用

页码：263 / 268

页数：6

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