Helicenes-A New Class of Organic Spin Filter

被引:341
作者
Kiran, Vankayala [1 ]
Mathew, Shinto P. [1 ]
Cohen, Sidney R. [2 ]
Delgado, Irene Hernandez [3 ]
Lacour, Jerome [3 ]
Naaman, Ron [1 ]
机构
[1] Weizmann Inst Sci, Dept Chem Phys, IL-76100 Rehovot, Israel
[2] Weizmann Inst Sci, Dept Chem Res Support, IL-76100 Rehovot, Israel
[3] Univ Geneva, Dept Organ Chem, Quai Ernest Ansermet 30, CH-1211 Geneva 4, Switzerland
关键词
DOUBLE-STRANDED DNA; ELECTRON TRANSMISSION; OPTICAL-PROPERTIES; SELECTIVITY; CHIRALITY; CHEMISTRY; DYES;
D O I
10.1002/adma.201504725
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral helicene, a fully conjugated system without stereogenic carbon, can filter spins effectively at room temperature, a consequence of the chiral-induced spin-selectivity effect. The chirality dictates the spin of the electrons transferred through helicene, and magnetoresistance devices based on these molecules show antisymmetric magnetoresistance versus H plots.
引用
收藏
页码:1957 / +
页数:7
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