Tunable self-assembly properties of amphiphilic phosphole alkynylgold(I) complexes through variation of the extent of the aromatic π-surface at the alkynyl moieties

被引：31

作者：

Hong, Eugene Yau-Hin

Wong, Hok-Lai

Yam, Vivian Wing-Wah ^{[1
]}

机构：

[1] Univ Hong Kong, Univ Grant Comm Hong Kong, Inst Mol Funct Mat, Areas Excellence Scheme, Hong Kong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 87期

关键词：

OPTOELECTRONIC PROPERTIES; GOLD(I); CHEMISTRY; OLIGOMERS; LUMINESCENCE; AGGREGATION;

D O I：

10.1039/c4cc05247a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new class of amphiphilic phosphole alkynylgold(I) complexes was synthesized and was demonstrated to display sheet-like nanostructures in aqueous DMSO solution. Modulation of the extent of the aromatic pi-surface at the alkynyl ligands was found to affect the self-assembly properties as well as the stability of the aggregates as revealed by the nucleation-elongation model.

引用

页码：13272 / 13274

页数：3

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