Exfoliation of ultrathin FePS3 layers as a promising electrocatalyst for the oxygen evolution reaction

被引：71

作者：

Zhu, Wen ^{[1
]}

Gan, Wei ^{[2
]}

Muhammad, Zahir ^{[1
]}

Wang, Changda ^{[1
]}

Wu, Chuanqiang ^{[1
]}

Liu, Hengjie ^{[1
]}

Liu, Daobin ^{[1
]}

Zhang, Ke ^{[1
]}

He, Qun ^{[1
]}

Jiang, Hongliang ^{[1
]}

Zheng, Xusheng ^{[1
]}

Sun, Zhe ^{[1
]}

Chen, Shuangming ^{[1
]}

Song, Li ^{[1
]}

机构：

[1] Univ Sci & Technol China, CAS Ctr Excellence Nanosci, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China

[2] Deakin Univ, Inst Frontier Mat, 75 Pigdons Rd, Waurn Ponds, Vic 3216, Australia

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 35期

关键词：

HYDROGEN EVOLUTION; WATER-OXIDATION; THIN-FILMS; BORON-NITRIDE; MOS2; TRANSITION; CATALYSTS; GRAPHENE; COBALT; CARBON;

D O I：

10.1039/c8cc01076e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Few-layer ternary FePS3 nanosheets, prepared via chemical vapor transport synthesis and ball-milling exfoliation, exhibit excellent electrocatalytic performance for the oxygen evolution reaction in an alkaline medium. Combined with first principles calculations, our X-ray spectroscopy and HRTEM results clearly reveal that the introduction of in-plane defects in FePS3 layers after exfoliation and formation of a FePS3-FeOOH heterostructure during the OER process largely contribute to the catalytic activity enhancement.

引用

页码：4481 / 4484

页数：4

共 33 条

[1] Ultrathin Graphene Layers Encapsulating Nickel Nanoparticles Derived Metal-Organic Frameworks for Highly Efficient Electrocatalytic Hydrogen and Oxygen Evolution Reactions [J].