Simultaneous catalytic degradation/reduction of multiple organic compounds by modifiable p(methacrylic acid-co-acrylonitrile)-M (M: Cu, Co) microgel catalyst composites

被引:63
作者
Ajmal, Muhammad [1 ]
Demirci, Sahin [2 ,3 ]
Siddiq, Mohammad [1 ]
Aktas, Nahit [4 ]
Sahiner, Nurettin [2 ,3 ]
机构
[1] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan
[2] Canakkale Onsekiz Mart Univ, Fac Sci & Arts, Dept Chem, Terzioglu Campus, TR-17100 Canakkale, Turkey
[3] Canakkale Onsekiz Mart Univ, Nanosci & Technol Res & Applicat Ctr NANORAC, Terzioglu Campus, TR-17100 Canakkale, Turkey
[4] Yuzuncu Yil Univ, Dept Chem Engn, TR-65080 Van, Turkey
关键词
NANOPARTICLE PREPARATION; SHELL PARTICLES; METAL-IONS; EOSIN Y; REDUCTION; REMOVAL; HYDROGELS; ACRYLONITRILE; POLYACRYLONITRILE; 4-NITROPHENOL;
D O I
10.1039/c5nj02298c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We prepared poly(methacrylic acid-co-acrylonitrile) (p(MAc-co-AN)) microgels by inverse suspension polymerization, and converted the nitrite groups into amidoxime groups to obtain more hydrophilic amidoximated poly(methacrylic acid-co-acrylonitrile) (amid-p(MAc-co-AN)) microgels. Amid-microgels were used as microreactors for in situ synthesis of copper and cobalt nanoparticles by loading Cu(II) and Co(II) ions into microgels from their aqueous metal salt solutions and then converted to their corresponding metal nanoparticles (MNPs) by treating the loaded metal ions with sodium borohydride (NaBH4). The characterization of the prepared microgels and microgel metal nanoparticle composites was carried out by SEM, TEM and TG analysis. The amounts of metal nanoparticles within microgels were estimated by MS measurements by dissolving the MNP entrapped within microgels by concentrated HCl acid treatment. Catalytic performances of the prepared amid-p(MAc-co-AN)-M (M: Cu, Co) microgel composites were investigated by using them as catalysts for the degradation of cationic and anionic organic dyes such as eosin Y (EY), methylene blue (MB) and methyl orange (MO), and for the reduction of nitro aromatic pollutants like 2-nitrophenol (2-NP) and 4-nitrophenol (4-NP) to their corresponding amino phenols. Here, we also report for the first time, the simultaneous degradation/reduction of MB, EY and 4-NP by amid-p(MAc-co-AN)-Cu microgel composites. Different parameters affecting the reduction rates such as metal types, the amount of catalysts, temperature and the amount of reducing agent were investigated.
引用
收藏
页码:1485 / 1496
页数:12
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