Mononuclear Zn(II) 3,5-Diiodosalicylate Complex with 3-Chloropyridine: Synthesis and Features of Non-Covalent Interactions in the Solid State

被引：5
|
作者：
Bondarenko, M. A. [1 ]
Novikov, A. S. [2 ]
Adonin, S. A. [1 ,3 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] St Petersburg State Univ, St Petersburg 199034, Russia
[3] South Ural State Univ, Chelyabinsk 454080, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 66卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
zinc complexes; N-donor ligands; halogen bond; crystal structure; quantum chemical calculations; COORDINATION POLYMERS; METAL-IONS; LUMINESCENT; ANIONS; SUBSTITUENTS; NICKEL(II); RADII; VAN;
D O I：
10.1134/S0036023621060061
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of zinc(II) nitrate with 3,5-diiodosalicylic acid in the presence of 3-chloropyridine gave the heteroligand complex [(3-ClPy)(2)ZnDISA(2)] (1), which was studied by X-ray diffraction. The crystal structure of 1 includes non-covalent I center dot center dot center dot O interactions (halogen bonds), the energies of which were estimated by quantum chemical calculations.
引用
收藏
页码：814 / 819
页数：6
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