Blending induced stack-ordering and performance improvement in a solution-processed n-type organic field-effect transistor

被引:23
作者
Wei, Zhongming [1 ,2 ]
Xi, Hongxia [1 ,2 ]
Dong, Huanli [1 ]
Wang, Linjun [1 ]
Xu, Wei [1 ]
Hu, Wenping [1 ]
Zhu, Daoben [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
基金
中国国家自然科学基金;
关键词
THIN-FILM TRANSISTORS; PERYLENE DIIMIDES; EFFECT MOBILITY; SEMICONDUCTORS; TRANSPORT; ELECTRON; TETRATHIAFULVALENE; DEVICES; DERIVATIVES; DESIGN;
D O I
10.1039/b918874f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The mobilities of the solution-processed n-type organic semiconductor, N,N'-di((Z)-9-octadecene)-3,4,9,10-perylene tetracarboxylic diimide (PTCDI-e), were dramatically improved (up to 30 times) by blending with electron donors. The reason can be assigned to the facilitated charge transport due to the increased stack-ordering and crystallinity of the spin-coated thin films after blending. This provides a new way to enhance the performance of existing organic semiconductors by intentional blending.
引用
收藏
页码:1203 / 1207
页数:5
相关论文
共 54 条
[1]   Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].
Allard, Sybille ;
Forster, Michael ;
Souharce, Benjamin ;
Thiem, Heiko ;
Scherf, Ullrich .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098
[2]   High electron mobility in room-temperature discotic liquid-crystalline perylene diimides [J].
An, ZS ;
Yu, JS ;
Jones, SC ;
Barlow, S ;
Yoo, S ;
Domercq, B ;
Prins, P ;
Siebbeles, LDA ;
Kippelen, B ;
Marder, SR .
ADVANCED MATERIALS, 2005, 17 (21) :2580-+
[3]   The larger acenes: Versatile organic semiconductors [J].
Anthony, John E. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :452-483
[4]   Device physics of polymer:fullerene bulk heterojunction solar cells [J].
Blom, Paul W. M. ;
Mihailetchi, Valentin D. ;
Koster, L. Jan Anton ;
Markov, Denis E. .
ADVANCED MATERIALS, 2007, 19 (12) :1551-1566
[5]   A UNIVERSAL RELATION BETWEEN CONDUCTIVITY AND FIELD-EFFECT MOBILITY IN DOPED AMORPHOUS ORGANIC SEMICONDUCTORS [J].
BROWN, AR ;
DELEEUW, DM ;
HAVINGA, EE ;
POMP, A .
SYNTHETIC METALS, 1994, 68 (01) :65-70
[6]   Ultralong nanobelts self-assembled from an asymmetric perylene tetracarboxylic diimide [J].
Che, Yanke ;
Datar, Aniket ;
Balakrishnan, Kaushik ;
Zang, Ling .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (23) :7234-+
[7]   Air stable n-channel organic semiconductors for thin film transistors based on fluorinated derivatives of perylene diimides [J].
Chen, H. Z. ;
Ling, M. M. ;
Mo, X. ;
Shi, M. M. ;
Wang, M. ;
Bao, Z. .
CHEMISTRY OF MATERIALS, 2007, 19 (04) :816-824
[8]   Organic thin film transistors based on N-alkyl perylene diimides:: Charge transport kinetics as a function of gate voltage and temperature [J].
Chesterfield, RJ ;
McKeen, JC ;
Newman, CR ;
Ewbank, PC ;
da Silva, DA ;
Brédas, JL ;
Miller, LL ;
Mann, KR ;
Frisbie, CD .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (50) :19281-19292
[9]   Organic light emitting field effect transistors: Advances and perspectives [J].
Cicoira, Fabio ;
Santato, Clara .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (17) :3421-3434
[10]   Semiconductors for organic transistors [J].
Facchetti, Antonio .
MATERIALS TODAY, 2007, 10 (03) :28-37