Chlorine doped graphitic carbon nitride nanorings as an efficient photoresponsive catalyst for water oxidation and organic decomposition

Rationally engineering the microstructure and electronic structure of catalysts to induce high activity for versatile applications remains a challenge. Herein, chlorine doped graphitic carbon nitride (Cl-doped g-C3N4) nanorings have been designed as a superior photocatalyst for pollutant degradation and oxygen evolution reaction ( OER). Remarkably, Cl-doped g-C3N4 nanorings display enhanced OER performance with a small overpotential of approximately 290 mV at current density of 10 mA cm(-2) and Tafel slope of 83 mV dec(-1), possessing comparable OER activity to precious metal oxides RuO2 and IrO2/C. The excellent catalytic performance of Cl-doped g-C 3 N 4 nanorings originates from the strong oxidation capability, abundant active sites exposed and efficient charge transfer. More importantly, visible light irradiation gives rise to a prominent improvement of the OER performance, reducing the OER overpotential and Tafel slope by 140 mV and 28 mV dec(-1), respectively, demonstrating the striking photo-responsive OER activity of Cl-doped g-C3N4 nanorings. The great photo-induced improvement in OER activity would be related to the efficient charge transfer and the ' OH radicals arising spontaneously on CN-Cl-100 catalyst upon light irradiation. This work establishes Cl-doped g-C3N4 nanorings as a highly competitive metal-free candidate for photoelectrochemical energy conversion and environmental cleaning application. (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.