Structural and spectroscopic characterization of (μ-hydroxo or μ-oxo)(μ-peroxo)diiron(IlI) complexes:: Models for peroxo intermediates of non-heme dilron proteins

被引：84

作者：

Zhang, X

Furutachi, H

Fujinami, S

Nagatomo, S

Maeda, Y

Watanabe, Y

Kitagawa, T

Suzuki, M ^{[1
]}

机构：

[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

[2] Okazaki Natl Res Inst, Ctr Integrat Biosci, Okazaki, Aichi 444 8585, Japan

[3] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan

[4] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 03期

关键词：

D O I：

10.1021/ja045594a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(μ-OH or μ-O)(μ-O2)(L)2]n+ were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes. Copyright © 2005 American Chemical Society.

引用

页码：826 / 827

页数：2

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