Structural and spectroscopic characterization of (μ-hydroxo or μ-oxo)(μ-peroxo)diiron(IlI) complexes:: Models for peroxo intermediates of non-heme dilron proteins

被引：84
|
作者：
Zhang, X
Furutachi, H
Fujinami, S
Nagatomo, S
Maeda, Y
Watanabe, Y
Kitagawa, T
Suzuki, M [1 ]
机构：
[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan
[2] Okazaki Natl Res Inst, Ctr Integrat Biosci, Okazaki, Aichi 444 8585, Japan
[3] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan
[4] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 03期
关键词：
D O I：
10.1021/ja045594a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(μ-OH or μ-O)(μ-O2)(L)2]n+ were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes. Copyright © 2005 American Chemical Society.
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收藏
页码：826 / 827
页数：2
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