Strategies from small-area to scalable fabrication for perovskite solar cells

被引：0

作者：

Yao, Huanhuan ^{[1
]}

Shi, Shenghuan ^{[1
]}

Li, Zhizai ^{[1
]}

Ci, Zhipeng ^{[1
]}

Zhu, Ge ^{[2
]}

Ding, Liming ^{[3
]}

Jin, Zhiwen ^{[1
]}

机构：

[1] Lanzhou Univ, Natl & Local Joint Engn Lab Opt Convers Mat & Tec, Key Lab Magnetism & Magnet Mat MoE, Sch Phys Sci & Technol,Key Lab Special Funct Mat, Lanzhou 730000, Gansu, Peoples R China

[2] Dalian Minzu Univ, Sch Phys & Mat Engn, Key Lab New Energy & Rare Earth Resource Utilizat, 18 Liaohe West Rd, Dalian 116600, Liaoning, Peoples R China

[3] Ctr Excellence Nanosci CAS, Natl Ctr Nanosci & Technol, Key Lab Nanosyst & Hierarch Fabricat CAS, Beijing 100190, Peoples R China

来源：

JOURNAL OF ENERGY CHEMISTRY | 2021年 / 57卷

基金：

中国国家自然科学基金;

关键词：

Large-area; Precursor solution; Preparation method; Solar module; HOLE-TRANSPORTING LAYER; LEAD HALIDE PEROVSKITE; HIGH-PERFORMANCE; HIGHLY EFFICIENT; THIN-FILMS; BASE ADDUCT; DEPOSITION; CH3NH3PBI3; STABILITY; ELECTRON;

D O I：

10.1016/j.jechem.2020.08.0332095-4956/

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Recently, perovskite solar cells (PSCs) have flourished, and their power conversion efficiency (PCE) has increased from the initial 3.8% to 25.2% in 2019, which is an unprecedented advance. However, usually high-efficiency and stable PSCs are small-area devices prepared by spin coating. This method is not suit-able for the preparation of large-area devices in commercialization. Therefore, there is an urgent need to develop new materials and methods for the scalable fabrication of PSCs. In this review, we first describe the common small-area PSCs preparation methods, understand the nucleation and crystal growth kinet-ics of perovskite, and analyze the reasons that hinder the development of small-area devices to large-area devices. Next, in order to meet the challenges of PSC's scalable fabrication, we summarize and analyze four strategies: scaling up precursor solutions, scalable deposition methods for large-area films, scaling up charge-transport layers and back electrodes, developing solar modules. Finally, challenges and pro-spects are proposed to help researchers prepare high-efficiency large-area PSCs. (c) 2020 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.

引用

页码：567 / 586

页数：20

共 143 条

[1] Viscosity, surface tension, density and contact angle of selected PbI2, PbCl2 and methylammonium lead halide perovskite solutions used in perovskite solar cells [J].