Kinetically stabilized hydrogen storage materials

被引：40

作者：

Graetz, Jason ^{[1
]}

Reilly, James J. ^{[1
]}

机构：

[1] Brookhaven Natl Lab, Dept Energy Sci & Technol, Upton, NY 11973 USA

来源：

SCRIPTA MATERIALIA | 2007年 / 56卷 / 10期

关键词：

hydrides; hydrogen storage; hydrogen desorption; differential scanning calorimetry (DSC); aluminum hydride;

D O I：

10.1016/j.scriptamat.2007.01.007

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Kinetically stabilized hydrides are characterized by a low reaction enthalpy and a decomposition reaction that is thermodynamically favorable under ambient conditions. The rapid, low temperature hydrogen evolution rates offer much promise for mobile proton exchange membrane fuel cell applications. However, a critical challenge exists to develop new methods to regenerate or recycle the hydride directly from the reactants and hydrogen gas. (c) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

引用

页码：835 / 839

页数：5

共 29 条

[1] Dehydrogenation kinetics of as-received and ball-milled LiAlH4 [J].

Andreasen, A ;

Vegge, T ;

Pedersen, AS .

JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (12) :3672-3678

[2] Effect of Ti-doping on the dehydrogenation kinetic parameters of lithium aluminum hydride [J].

Andreasen, Anders .

JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 419 (1-2) :40-44

[3] DIRECT SYNTHESIS OF AMINE ALANES [J].

ASHBY, EC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (09) :1882-&

[4] DIRECT SYNTHESIS OF COMPLEX METAL HYDRIDES [J].

ASHBY, EC ;

REDMAN, HE ;

BRENDEL, GJ .

INORGANIC CHEMISTRY, 1963, 2 (03) :499-&

[5] THE EQUILIBRIUM BETWEEN SOLID ALUMINUM-HYDRIDE AND GASEOUS-HYDROGEN [J].

BARANOWSKI, B ;

TKACZ, M .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-WIESBADEN, 1983, 135 :27-38

[6] Hydrogen in aluminum [J].

Birnbaum, HK ;

Buckley, C ;

Zeides, F ;

Sirois, E ;

Rozenak, P ;

Spooner, S ;

Lin, JS .

JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 253 :260-264

[7] Isothermal decomposition of LiAlD4 with and without additives [J].

Blanchard, D ;

Brinks, HW ;

Hauback, BC ;

Norby, P ;

Muller, J .

JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 404 :743-747

[8] Metal-doped sodium aluminium hydrides as potential new hydrogen storage materials [J].

Bogdanovic, B ;

Brand, RA ;

Marjanovic, A ;

Schwickardi, M ;

Tölle, J .

JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 302 (1-2) :36-58

[9] PREPARATION AND PROPERTIES OF ALUMINUM-HYDRIDE [J].

BROWER, FM ;

MATZEK, NE ;

REIGLER, PF ;

RINN, HW ;

ROBERTS, CB ;

SCHMIDT, DL ;

SNOVER, JA ;

TERADA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (09) :2450-2453

[10] ALANAT-SYNTHESE AUS DEN ELEMENTEN UND IHRE BEDEUTUNG [J].

CLASEN, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1961, 73 (10) :322-&

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