Synthesis of a Re-Pt2 complex with bridging sulfido ligands

被引：5

作者：

Pawlicki, SH ^{[1
]}

Noll, BC ^{[1
]}

Dubois, RM ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 01期

关键词：

trimetallic; rhenium; platinum; mu-sulfido; oxo;

D O I：

10.1080/0095897021000039089

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cp'ReCl2S3 (where Cp'= C5EtMe4) with Pt(PPh3)(3) in toluene in air results in the formation of the heteronuclear product [Cp'ReO(mu(3)-S)(2)Pt-2(PPh3)(3)Cl]ReO4, 1. The product has been characterized by spectroscopic methods, cyclic voltammetry and by an X-ray diffraction study. The cation contains an unusual triangular array of one rhenium and two platinum ions with one Pt-Re bond. Under the same reaction conditions, the reaction of the known platinum dimer (PPh3)(4)Pt-2(mu-S)(2) with Cp'ReOCl2 was unsuccessful as a route to the cation of 1.

引用

页码：41 / 47

页数：7

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