Scalable bio-friendly method for production of homogeneous metal oxide nanoparticles using green bovine skin gelatin

被引：24

作者：

Alnarabiji, Mohamad Sahban ^{[1
]}

Yahya, Noorhana ^{[2
]}

Hamed, Yaman ^{[2
]}

Ardakani, Seyed Esmaeil Mandavi ^{[2
]}

Azizi, Khairun ^{[1
]}

Klemes, Jiri Jaromir ^{[3
]}

Abdullah, Bawadi ^{[1
]}

Tasfy, Sara Faiz Hanna ^{[4
]}

Abd Hamid, Sharifa Bee ^{[5
]}

Nashed, Omar ^{[1
]}

机构：

[1] Univ Teknol PETRONAS, Dept Chem Engn, Tronoh 31750, Perak Darulridz, Malaysia

[2] Univ Teknol PETRONAS, Dept Fundamental & Appl Sci, Tronoh 31750, Perak Darulridz, Malaysia

[3] Pazmany Peter Catholic Univ, Szentkiralyi Utca 28, H-1088 Budapest, Hungary

[4] Amer Univ Ras Al Khaimah, Dept Chem & Petr Engn, Ras Al Khaymah 10021, U Arab Emirates

[5] Univ Malaya, Inst Postgrad Studies, Nanotechnol & Catalysis Res Ctr NANOCAT, Kuala Lumpur 50603, Malaysia

来源：

JOURNAL OF CLEANER PRODUCTION | 2017年 / 162卷

关键词：

Zinc oxide nanoparticles; Isoelectric point (IEP); Bovine skin gelatin type B; Monodispersed; Statistical analysis; ZINC-OXIDE; ZNO NANOPARTICLES; SOL-GEL; THERMAL-CONDUCTIVITY; MAGNETIC-PROPERTIES; FILMS; NANOCATALYST; ENHANCEMENT; CATALYST; AMMONIA;

D O I：

10.1016/j.jclepro.2017.06.010

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The use of bovine skin gelatin in the synthesis of variety of nanostructures is a bio-friendly approach. In the current study, we investigated experimentally, for the first time, scalable process for production of homogeneous hexagonal zinc oxide nanoparticles (ZnO-NPs) not only with narrow size distribution and simple process but also cost effective and bio-friendly by green sol-gel method utilizing bovine skin gelatin (BSGB) matrix. Statistical analysis was done to evaluate the reliability of measuring the particle size using X-ray Diffraction analysis (XRD) and/or surface area (BET) instead of High Resolution Transmission Electron Microscope (HRTEM) and the following novel points are found. Impressively mono-dispersed ZnO-NPs with hexagonal structure were synthesized by adjusting the pH. All the samples exhibited hexagonal (wurtzite) crystal shape while the obtained morphology of the particles varies from hexagonal NPs to combination of hexagonal NPs and rod-like particles with reducing the pH from 6 to 2 due to the variation of bloom strength of the gelatin. Long chain gelatin contributed to suppressing the growth of nanoparticle and controlling the morphology. We discovered statistically that there was insignificant difference in measuring the particle size using XRD and HRTEM which can save time, energy, and cost at industrial aspect. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：186 / 194

页数：9

共 59 条

[1] The enhancement of the magnetic properties of α-Fe2O3 nanocatalyst using an external magnetic field for the production of green ammonia [J].

Alciasem, Bilal ;

Yahya, Noorhana ;

Qureshi, Saima ;

Irfan, Muhammad ;

Rehman, Zia Ur ;

Soleimani, Hassan .

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2017, 217 :49-62

[2]

Alias S.S., 2014, ZNO EFFECTS PH SOL G, P9

[3] Micro-Raman investigation of optical phonons in ZnO nanocrystals [J].

Alim, KA ;

Fonoberov, VA ;

Shamsa, M ;

Balandin, AA .

JOURNAL OF APPLIED PHYSICS, 2005, 97 (12)

[4] Perspectives on the physical chemistry of semiconductor nanocrystals [J].

Alivisatos, AP .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239

[5]

Alnarabiji M.S., 2014, ROLE SURFACE AREA ZN, P201

[6] The Influence of Hydrophobic Multiwall Carbon Nanotubes Concentration on Enhanced Oil Recovery [J].

Alnarabiji, Mohamad Sahban ;

Yahya, Noorhana ;

Shafie, Afza ;

Solemani, Hassan ;

Chandran, Kayathiri ;

Abd Hamid, Sharifah Bee ;

Azizi, Khairun .

PROCEEDING OF 4TH INTERNATIONAL CONFERENCE ON PROCESS ENGINEERING AND ADVANCED MATERIALS (ICPEAM 2016), 2016, 148 :1137-1140

[7] Thermal degradation of edible films based on milk proteins and gelatin in inert atmosphere [J].

Barreto, PLM ;

Pires, ATN ;

Soldi, V .

POLYMER DEGRADATION AND STABILITY, 2003, 79 (01) :147-152

[8] The first organically templated open-framework metal selenate with a three-dimensional architecture [J].

Behera, JN ;

Ayi, AA ;

Rao, CNR .

CHEMICAL COMMUNICATIONS, 2004, (08) :968-969

[9] Determination of nanocrystal sizes:: A comparison of TEM, SAXS, and XRD studies of highly monodisperse COPt3 particles [J].

Borchert, H ;

Shevehenko, EV ;

Robert, A ;

Mekis, I ;

Kornowski, A ;

Grübel, G ;

Weller, H .

LANGMUIR, 2005, 21 (05) :1931-1936

[10] Influence of green catalyst on transesterification process using ultrasonic-assisted [J].

Chuah, Lai Fatt ;

Amin, Maridah Mohd ;

Yusup, Suzana ;

Raman, Nur' Aini ;

Bokhari, Awais ;

Klemes, Jiri Jaromir ;

Alnarabiji, Mohamad Sahban .

JOURNAL OF CLEANER PRODUCTION, 2016, 136 :14-22

← 1 2 3 4 5 6 →