Overview on the Removal of Iron from Phosphoric Acid: A Comparative Study

被引：5
作者：
Ahmed, I. M. [1 ,2 ]
机构：
[1] Jouf Univ, Coll Sci, Chem Dept, Sakaka, Saudi Arabia
[2] Egyptian Atom Energy Author, Hot Labs & Waste Management Ctr, Cairo, Egypt
来源：
ARAB JOURNAL OF NUCLEAR SCIENCES AND APPLICATIONS | 2021年 / 54卷 / 02期
关键词：
Phosphoric acid; Iron; Precipitation; Sorption; Solvent extraction; WET-PROCESS; SOLVENT-EXTRACTION; HYDROCHLORIC-ACID; PURIFICATION; EQUILIBRIUM; MEMBRANE; RECOVERY; FE(III); PRECIPITATION; ADSORPTION;
D O I：
10.21608/ajnsa.2020.43903.1404
中图分类号：
TL [原子能技术]; O571 [原子核物理学];
学科分类号：
0827 ; 082701 ;
摘要：
Wet process phosphoric acid (WPA) represents the main route for phosphate fertilizers world's production using sulfuric acid as leaching agent. The produced acid is contaminated with various metal ions as iron, aluminum, cadmium, arsenic, uranium, etc. that limit its use in metal finishing, food, cosmetics and electronic industries. Hence, purification of the wet phosphoric acid is a challenge task. The presence of high concentration of iron in phosphoric acid leads to many problems that affect the production process as increasing the viscosity, decreasing the filtration ration rate, formation of precipitates during concentration, clarification and storage, P2O5 loss in addition to decreasing the solubility of fertilizers, The present review gives an overview on the removal of iron from crude phosphoric acid by some commonly used techniques including precipitation, sorption and solvent extraction to evaluate the efficiency and drawbacks of each process. The pre- treatments of phosphoric acid are also discussed.
引用
收藏
页码：37 / 49
页数：13
相关论文
共 77 条
[1]  
Aal EAA, 1999, MINER METALL PROC, V16, P44
[2]   Increasing the filtration rate of phospho-gypsum using surfactant [J].
Abdel-Aal, E. A. ;
Mahmoud, M. M. H. ;
Ei-Shall, H. ;
Ismail, A. K. .
HYDROMETALLURGY, 2007, 85 (01) :53-58
[3]   Purification of high iron wet-process phosphoric acid via oxalate precipitation method [J].
Abdel-Ghafar, H. M. ;
Abdel-Aal, E. A. ;
Ibrahim, M. A. M. ;
El-Shall, H. ;
Ismail, A. K. .
HYDROMETALLURGY, 2019, 184 :1-8
[4]  
Abdel-Ghafar H. M., 2018, EGYPT J PET, V27, P1235, DOI [10.1016/j.ejpe.2018.06.001, DOI 10.1016/J.EJPE.2018.06.001]
[5]  
Abdennebi N., 2017, Journal of materials and Environmental Sciences, V8, P557
[6]   Purification of wet process phosphoric acid by solvent extraction with TBP and MIBK mixtures [J].
Ahmed, Hannachi ;
Diamonta, Habaili ;
Chaker, Chtara ;
Abdelhamid, Ratel .
SEPARATION AND PURIFICATION TECHNOLOGY, 2007, 55 (02) :212-216
[7]   Modification of perlite to prepare low cost zeolite as adsorbent material for removal of 144Ce and 152+154Eu from aqueous solution [J].
Ahmed, I. M. ;
Attia, Lamis A. ;
Attallah, M. F. .
RADIOCHIMICA ACTA, 2020, 108 (09) :727-735
[8]   Adsorption study of anionic reactive dye from aqueous solution to Mg-Fe-CO3 layered double hydroxide (LDH) [J].
Ahmed, I. M. ;
Gasser, M. S. .
APPLIED SURFACE SCIENCE, 2012, 259 :650-656
[9]   Purification of Crude Phosphoric Acid and Leached Apatite by Solvent Extraction with CYANEX 923 in Kerosene [J].
Ahmed, Ismail M. ;
Ammanoeil, Romany N. ;
Saad, Ebtissam A. ;
Daoud, Jacqueline A. .
PERIODICA POLYTECHNICA-CHEMICAL ENGINEERING, 2019, 63 (01) :122-129
[10]   Hybrid precipitation-nanofiltration treatment of effluent pond water from phosphoric acid industry [J].
Al-Harahsheh, Mohammad ;
Hussain, Yazan A. ;
Al-Zoubi, Habis ;
Batiha, Marwan ;
Hammouri, Esraa .
DESALINATION, 2017, 406 :88-97
12345678