Kinetics and mechanism of the ruthenium(III) catalyzed oxidation of propane-1,3-diol by alkaline hexacyanoferrate(III)

被引：3
作者：
Mucientes, AE
Poblete, FJ
Santiago, F
Casado, J
机构：
[1] Univ Castilla La Mancha, Fac Quim, Dept Quim Fis, E-13071 Ciudad Real, Spain
[2] Univ Salamanca, Fac Quim, Dept Quim Fis, E-37008 Salamanca, Spain
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 62卷 / 02期
关键词：
kinetics; catalytic oxidation; alcohols; Ru(III);
D O I：
10.1007/BF02475466
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of oxidation of propane-1,3-diol by alkaline hexacyanoferrate (III) catalyzed by ruthenium trichloride has been studied spectrophotometrically. A reaction mechanism involving the formation of an intermediate complex between the substrate and the catalyst is proposed. In the rate-determining step this complex is attacked by hexacyanoferrate (III) forming a free radical which is further oxidized.
引用
收藏
页码：293 / 297
页数：5
相关论文
共 50 条
  • [41] Ruthenium (III) catalysed and uncatalysed oxidation of torsemide by hexacyanoferrate (III) in aqueous alkaline medium: A kinetic comparative approach
    Ravindra, K. S.
    Shastry, Vidyavati A.
    Kumar, Mohan
    Nagarajaiah, H.
    Ramyashree, H.
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2021, 98 (08)
  • [42] Kinetics and Mechanism of Oxidation of Captopril by Hexacyanoferrate(III) in Aqueous Acidic Medium
    Seema S. Badi
    Suresh M. Tuwar
    Journal of Solution Chemistry, 2013, 42 : 1518 - 1531
  • [43] Kinetics and Mechanism of Oxidation of Hydroxyurea Derivatives with Hexacyanoferrate(III) in Aqueous Solution
    Budimir, Ana
    Weitner, Tin
    Kos, Ivan
    Sakic, Davor
    Gabricevic, Mario
    Besic, Erim
    Birus, Mladen
    CROATICA CHEMICA ACTA, 2011, 84 (02) : 133 - 147
  • [44] Kinetics and Mechanism of Oxidation of Captopril by Hexacyanoferrate(III) in Aqueous Acidic Medium
    Badi, Seema S.
    Tuwar, Suresh M.
    JOURNAL OF SOLUTION CHEMISTRY, 2013, 42 (07) : 1518 - 1531
  • [45] Kinetics of Ruthenium(III) Catalyzed and Uncatalyzed Oxidation of Monoethanolamine by N-Bromosuccinimide
    Nadh, R. Venkata
    Sundar, B. Syama
    Radhakrishnamurti, P. S.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 90 (09) : 1760 - 1765
  • [46] Kinetics and Mechanism of Oxidation of Hydroxyurea with Hexacyanoferrate(III) Ions in Aqueous Solution
    Budimir, Ana
    Besic, Erim
    Birus, Mladen
    CROATICA CHEMICA ACTA, 2009, 82 (04) : 807 - 818
  • [47] Kinetic Investigations of Ruthenium(III) Catalyzed Oxidation of Dimedone by Diperiodatocuprate(III) in Aqueous Alkaline Media
    Santosh B. Konnur
    Sharanappa T. Nandibewoor
    Russian Journal of Physical Chemistry A, 2019, 93 : 1686 - 1698
  • [48] Kinetics and mechanism of oxidation of captopril by diperiodatocuprate(III) in aqueous alkaline medium
    Angadi, Mahantesh A.
    Tuwar, Suresh M.
    MONATSHEFTE FUR CHEMIE, 2015, 146 (02): : 219 - 229
  • [49] A kinetic study of iridium(III) chloride catalyzed oxidation of diethylene glycol by hexacyanoferrate(III) in aqueous alkaline medium
    Goel, A
    Chauhan, M
    ASIAN JOURNAL OF CHEMISTRY, 2004, 16 (02) : 1200 - 1202
  • [50] Desymmetrization of a Propane-1,3-diol to Introduce the Quaternary Chiral Center of an AMG 176 Drug Substance Intermediate
    Ananthoji, Padmini K. K.
    Arunachalampillai, Athimoolam
    Beaver, Matthew G. G.
    Fang, Yuan-Qing
    Hedley, Simon J. J.
    Lucas, Brian S. S.
    Tedrow, Jason S. S.
    Faul, Margaret M. M.
    SYNTHESIS-STUTTGART, 2023, 55 (15): : 2397 - 2405
12345