Blue shift of optical band gap in Er-doped ZnO thin films deposited by direct current reactive magnetron sputtering technique

被引:51
作者
Chen, Y. [1 ]
Xu, X. L. [2 ]
Zhang, G. H. [1 ]
Xue, H. [1 ]
Ma, S. Y. [2 ]
机构
[1] NW Univ Nationality, State Natl Affairs Commiss PRC, Key Lab Elect Mat, Lanzhou 730030, Gansu, Peoples R China
[2] NW Normal Univ, Coll Phys & Elect Engn, Lanzhou 730070, Gansu, Peoples R China
关键词
Er-doped ZnO films; Substrate temperatures; Structural properties; Optical properties; CHEMICAL-VAPOR-DEPOSITION; ZINC-OXIDE FILMS; PLASMA; RF; AL;
D O I
10.1016/j.physe.2010.01.029
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Er-doped ZnO films were deposited by direct current co-reactive magnetron sputtering technique and the microstructure and the optical properties of the ZnO films were investigated. XRD analysis reveals that the substrate temperatures have an evident effect on the (0 0 2) preferential orientation and the Er-doped ZnO film deposited at room temperature consists of an amorphous phase. The blue shift of the optical band gap was observed in the ZnO:Er films compared with undoped ZnO film, and the Er-doped ZnO film deposited at room temperature has the largest band gap (about 3.99 eV). The main reason for the broadening of the band gap is attributed to the amorphous phase in the Er-doped ZnO film. Meanwhile, the red shift of the band gap in the ZnO:Er films deposited at high temperature was observed as the crystallinity of the fim became better. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1713 / 1716
页数:4
相关论文
共 20 条
[2]   Al-doped zinc oxide films deposited by simultaneous rf and dc excitation of a magnetron plasma: Relationships between plasma parameters and structural and electrical film properties [J].
Cebulla, R ;
Wendt, R ;
Ellmer, K .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (02) :1087-1095
[3]   Electrical and optical properties of ZnO thin films prepared by magnetron rf sputtering - influence of Al, Er and H [J].
Dimova-Malinovska, D. ;
Nichev, H. ;
Angelov, O. ;
Grigorov, V. ;
Kamenova, A. .
SUPERLATTICES AND MICROSTRUCTURES, 2007, 42 (1-6) :123-128
[4]   X-RAY PHOTOEMISSION SPECTROSCOPY STUDIES OF SN-DOPED INDIUM-OXIDE FILMS [J].
FAN, JCC ;
GOODENOUGH, JB .
JOURNAL OF APPLIED PHYSICS, 1977, 48 (08) :3524-3531
[5]   XPS and X-ray diffraction studies of aluminum-doped zinc oxide transparent conducting films [J].
Islam, MN ;
Ghosh, TB ;
Chopra, KL ;
Acharya, HN .
THIN SOLID FILMS, 1996, 280 (1-2) :20-25
[6]   Influence of growth mode on the structural, optical, and electrical properties of In-doped ZnO nanorods [J].
Jung, M. N. ;
Koo, J. E. ;
Oh, S. J. ;
Lee, B. W. ;
Lee, W. J. ;
Ha, S. H. ;
Cho, Y. R. ;
Chang, J. H. .
APPLIED PHYSICS LETTERS, 2009, 94 (04)
[7]   Transparent conducting Zr-doped In2O3 thin films for organic light-emitting diodes [J].
Kim, H ;
Horwitz, JS ;
Kushto, GP ;
Qadri, SB ;
Kafafi, ZH ;
Chrisey, DB .
APPLIED PHYSICS LETTERS, 2001, 78 (08) :1050-1052
[8]   Self-organized ZnO quantum dots on SiO2/Si substrates by metalorganic chemical vapor deposition [J].
Kim, SW ;
Fujita, S ;
Fujita, S .
APPLIED PHYSICS LETTERS, 2002, 81 (26) :5036-5038
[9]   Highly erbium-doped zinc-oxide thin film prepared by laser ablation and its 1.54 μm emission dynamics [J].
Komuro, S ;
Katsumata, T ;
Morikawa, T ;
Zhao, XW ;
Isshiki, H ;
Aoyagi, Y .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (12) :7129-7136
[10]   EFFECT OF HYDROGEN PLASMA TREATMENT ON TRANSPARENT CONDUCTING OXIDES [J].
MAJOR, S ;
KUMAR, S ;
BHATNAGAR, M ;
CHOPRA, KL .
APPLIED PHYSICS LETTERS, 1986, 49 (07) :394-396