ESR spectroscopy for monitoring the photochemical and thermal degradation of conjugated polymers used as electron donor materials in organic bulk heterojunction solar cells

被引：59

作者：

Frolova, Lyubov A. ^{[1
]}

Piven, Natalia P. ^{[2
]}

Susarova, Diana K. ^{[1
]}

Akkuratov, Alexander V. ^{[1
]}

Babenko, Sergey D. ^{[2
]}

Troshin, Pavel A. ^{[1
]}

机构：

[1] IPCP RAS, Chernogolovka 141432, Russia

[2] RAS, Inst Energy Problems Chem Phys Branch, Chernogolovka 142432, Russia

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 12期

关键词：

PARAMAGNETIC-RESONANCE; CHARGE-CARRIERS; LIGHT; DESIGN; COMPOSITES; STABILITY; CUGASE2; STATES; EPR;

D O I：

10.1039/c4cc08146c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was shown that ESR spectroscopy is a very useful technique for monitoring the photochemical and thermal degradation of conjugated polymers commonly used in organic solar cells. The relative stability of materials can be quantified by comparing the rates of trap accumulation (dC(R)/dt) estimated from their ESR profiles.

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收藏

页码：2242 / 2244

页数：3

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