Syntheses and characterization of biodiesel from citrus sinensis seed oil

被引:25
作者
Ezekoye, Veronica [1 ]
Adinde, Rita [1 ]
Ezekoye, David [2 ]
Ofomatah, Anthony [3 ]
机构
[1] Univ Nigeria, Dept Phys & Astron, Nsukka, Nigeria
[2] Univ Nigeria, Dept Civil Engn, Nsukka, Nigeria
[3] Univ Nigeria, Natl Ctr Energy Res & Dev, Nsukka, Nigeria
关键词
Citrus sinensis seed oil; Biodiesel; Physicochemical properties; Transesterification; VEGETABLE-OILS; TRANSESTERIFICATION; FUEL;
D O I
10.1016/j.sciaf.2019.e00217
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Citrus sinensis seed oil (CSSO) was extracted using Soxhlet extraction method with n-hexane as solvent at 66.0 degrees C. The extracted CSSO was converted into biodiesel using alkali-catalytic-transesterification method at a constant of temperature of 60 degrees C for 60 min. The oil yield was 34.00% while biodiesel yield was 76.93%. The physicochemical properties of the analysed biodiesel were specific gravity (899), density (900 kg/m(3)) at 30.0 degrees C, kinematic viscosity (3.79 mm(2)/s) at 40.0 degrees C, flash point (190.0 degrees C), pour point (-6.0 degrees C), cloud point (-2.0 degrees C), acid value (0.1 mgKOH/g), iodine value (119.05), ash content (0.1%), moisture content (0.1%), calorific value (35,471.45 KJ/kg), sulphur content (0.001), initial/final boiling (200/203 degrees C), Calcium Ca (18.00 mg/kg), Magnesium Mg (1.64 mg/kg), Potassium K (4.33 mg/kg), Sodium Na (0.09 mg/kg) and Phosphorus P (0.11 mg/kg) Gas Chromatograph (GC) was used to determine biodiesel compositions. Infrared spectroscopy was used for the detection of functional groups and identification of organic compounds. The quality parameters of the biodiesel were found to be within international acceptable ASTM 6751 and EN14214 standards. The Citrus sinensis seed (CSS) is a good feedstock for biodiesel production. (c) 2019 The Authors. Published by Elsevier B.V. on behalf of African Institute of Mathematical Sciences / Next Einstein Initiative. This is an open access article under the CC BY license. (http://creativecommons.org/licenses/by/4.0/)
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页数:8
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