Mechanical Behavior and Transport Properties of Cementitious Composites Reinforced with Carbon Nanotubes

被引:42
作者
Ahmed, Hawreen [1 ]
Bogas, Jose Alexandre [1 ]
Guedes, Mafalda [2 ,3 ,4 ]
机构
[1] Univ Lisbon, Inst Super Tecn, DECivil, Civil Engn Res & Innovat Sustainabil, Av Rovisco Pais, P-1049001 Lisbon, Portugal
[2] Inst Politecn Setubal, Ctr Prod Dev & Technol Transfer, P-2914761 Estefanilha, Setubal, Portugal
[3] Inst Politecn Setubal, Dept Mech Engn, Setubal Sch Technol, P-2914761 Estefanilha, Setubal, Portugal
[4] Univ Lisbon, Inst Super Tecn, Ctr Phys & Engn Adv Mat, Av Rovisco Pais 1, P-1049001 Lisbon, Portugal
关键词
Carbon nanotube; Cementitious composite; Mechanical strength; Water absorption; Shrinkage; Microstructure; Thermogravimetric analysis; PORTLAND-CEMENT; FLEXURAL STRENGTH; DRYING SHRINKAGE; DISPERSION; MICROSTRUCTURE; CONCRETE; PASTE; NANOPARTICLES; DEHYDRATION; TEMPERATURE;
D O I
10.1061/(ASCE)MT.1943-5533.0002470
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The mechanical behavior and transport properties of cement pastes reinforced with various types and amounts of pristine and functionalized carbon nanotubes (CNTs) are characterized for different water to cement (w/c) ratios. The flexural strength, compressive strength, and dynamic modulus of elasticity of CNT-reinforced cement pastes were up to 38%, 58%, and 22% higher than those of unreinforced pastes, respectively. CNTs were also effective in decreasing the drying shrinkage of cement pastes to 87% lower than that of reference pastes at early ages. Water absorption by immersion and capillary absorption could be also reduced as much as 16% and 38%, respectively. Microstructure and thermogravimetric analysis evidenced effective dispersion, microcrack bridging, and nucleation effects of CNT-reinforced cement matrices. Results show that depending on the type and dispersion procedure, CNTs effectively contribute for the reinforcement of cementitious materials, regardless of w/c ratio.
引用
收藏
页数:14
相关论文
共 60 条
[1]   On the aspect ratio effect of multi-walled carbon nanotube reinforcements on the mechanical properties of cementitious nanocomposites [J].
Abu Al-Rub, Rashid K. ;
Ashour, Ahmad I. ;
Tyson, Bryan M. .
CONSTRUCTION AND BUILDING MATERIALS, 2012, 35 :647-655
[2]   Dispersion and reinforcement efficiency of carbon nanotubes in cementitious composites [J].
Ahmed, Hawreen ;
Bogas, Jose Alexandre ;
Guedes, Mafalda ;
Costa Pereira, Manuel Francisco .
MAGAZINE OF CONCRETE RESEARCH, 2019, 71 (08) :408-423
[3]   The use of thermal analysis in assessing the effect of temperature on a cement paste [J].
Alarcon-Ruiz, L ;
Platret, G ;
Massieu, E ;
Ehrlacher, A .
CEMENT AND CONCRETE RESEARCH, 2005, 35 (03) :609-613
[4]   Influence of mineral additions and different compositional parameters on the shrinkage of structural expanded clay lightweight concrete [J].
Alexandre Bogas, J. ;
Nogueira, Rita ;
Almeida, Nuno G. .
MATERIALS & DESIGN, 2014, 56 :1039-1048
[5]   Dehydration and rehydration processes of cement paste exposed to high temperature environments [J].
Alonso, C ;
Fernandez, L .
JOURNAL OF MATERIALS SCIENCE, 2004, 39 (09) :3015-3024
[6]  
[Anonymous], P MAT 18 C SOC PORT
[7]  
[Anonymous], 2016, 1 C TESTS EXPERIMEN
[8]  
[Anonymous], 2005, DES CONCR STRUCT
[9]  
ASTM, 2015, E187601 ASTM
[10]   The influence of ion chloride on concretes made with sulfate-resistant cements and mineral admixtures [J].
Bernal Camacho, J. ;
Mahmoud Abdelkader, S. ;
Reyes Pozo, E. ;
Moragues Terrades, A. .
CONSTRUCTION AND BUILDING MATERIALS, 2014, 70 :483-493