The para-fluoro-thiol reaction as a powerful tool for precision network synthesis

被引：22

作者：

Cavalli, Federica ^{[1
]}

Mutlu, Hatice ^{[1
,2
]}

Steinmueller, Sven O. ^{[3
]}

Barner, Leonie ^{[1
,4
,5
]}

机构：

[1] KIT, Inst Biol Grenzflachen, Soft Matter Synth Lab, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

[2] KIT, Inst Tech Chem & Polymerchem, Macromol Architectures, Engesserstr 18, D-76128 Karlsruhe, Germany

[3] KIT, Inst Appl Mat, Surface Anal Grp, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany

[4] QUT, Sch Chem Phys & Mech Engn, 2 George St, Brisbane, Qld 4000, Australia

[5] QUT, Inst Future Environm, 2 George St, Brisbane, Qld 4000, Australia

来源：

POLYMER CHEMISTRY | 2017年 / 8卷 / 25期

关键词：

D O I：

10.1039/c7py00812k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We introduce the regioselective para-fluoro-thiol reaction (PFTR) as a novel strategy for network formation. Here, a novel fluorinated linker is designed and further reacted with several bifunctional thiols to demonstrate the versatility of the method. Critically, the formation of the networks is evidenced by XPS and ToF-SIMS.

引用

收藏

页码：3778 / 3782

页数：5

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