Kinetics of the interaction of platinium(II) bromide complexes with potassium iodide

被引:0
作者
Gel'fman, MI [1 ]
Salishcheva, OV [1 ]
Moldagulova, NE [1 ]
机构
[1] Kemerovo Tech Inst Food Ind, Kemerovo, Russia
关键词
D O I
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction kinetics of dimeric complex [enPtBr(2)Pten](NO3)(2) with KI in aqueous solutions at 21, 35, and 45degreesC are studied. The rate constants and activation energies of the reaction are found. The reaction kinetics of [PtenBr(2)] with KI are studied under the same conditions. It is shown that the bridging bromine atoms are substituted more rapidly than the terminal atoms.
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页码:1342 / 1345
页数:4
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